1-phenyl-2-carboxy-1,2-dicarba-closo-dodecaborane⁽¹²⁾

Base Information

Chemical Name:1-phenyl-2-carboxy-1,2-dicarba-closo-dodecaborane⁽¹²⁾
CAS No.:23810-08-4
Molecular Formula:C₉H₁₆B₁₀O₂
Molecular Weight:264.335
Hs Code.:

1-phenyl-2-carboxy-1,2-dicarba-closo-dodecaborane<sup>(12)</sup>

Synonyms:1-phenyl-2-carboxy-1,2-dicarba-closo-dodecaborane⁽¹²⁾

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Chemical Property of 1-phenyl-2-carboxy-1,2-dicarba-closo-dodecaborane⁽¹²⁾

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Technology Process of 1-phenyl-2-carboxy-1,2-dicarba-closo-dodecaborane⁽¹²⁾

There total 2 articles about 1-phenyl-2-carboxy-1,2-dicarba-closo-dodecaborane⁽¹²⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 23841-89-6
1-phenyl-2-trimethylsilyl-1,2-dicarba-closo-dodecaborane⁽¹²⁾

: 23810-08-4
1-phenyl-2-carboxy-1,2-dicarba-closo-dodecaborane⁽¹²⁾

Guidance literature:: With n-butyllithium; carbon dioxide; In diethyl ether; benzene; byproducts: nBuSiMe3; (Ar); refluxing (2 h), pouring into ether/solid CO2; addn. 2% KOH, pptn.on HCl addn., extn. (ether), recrystn. (heptane); elem. anal.;
DOI:10.1007/BF02495657

Reference yield: 56.0%

: 16390-61-7
1-phenyl-1,2-closo-C₂B₁₀H₁₁

: 124-38-9,18923-20-1
carbon dioxide

: 23810-08-4
1-phenyl-2-carboxy-1,2-dicarba-closo-dodecaborane⁽¹²⁾

Guidance literature:: With nBuLi; aq. HCl; In toluene; all manipulations under dry N2 atm.; 11 equivalent of soln. of MeLi added to soln. of B compd. at 0°C soln. allowed to warm to room temp.and gaseous CO2 bubbled through soln. for 20-30 min, hydrolysed with 2 M aq. HCl; etheral layer sepd., dried over MgSO4 overnight, solvent removed; recrystd. from petroleum ether; elem. anal.;
DOI:10.1016/j.poly.2003.10.016

Reference yield: 99.0%

: 23810-08-4
1-phenyl-2-carboxy-1,2-dicarba-closo-dodecaborane⁽¹²⁾

: 19226-36-9
3-phenyl-5H-1,4,2-dioxazol-5-one

: C₁₅H₂₁B₁₀NO

Guidance literature:: With silver hexafluoroantimonate; bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; sodium acetate; for 1h; Milling;
DOI:10.1021/acs.orglett.1c03336