[Cu(bis[2-(diphenylphosphino)phenyl]ether)₂]tetrafluoroborate

Base Information

• Chemical Name: [Cu(bis[2-(diphenylphosphino)phenyl]ether)₂]tetrafluoroborate
• CAS No.: 947372-37-4
• Molecular Formula: BF₄*C₇₂H₅₆CuO₂P₄
• Molecular Weight: 1227.48
• Mol file: 947372-37-4.mol

Synonyms:[Cu(bis[2-(diphenylphosphino)phenyl]ether)₂]tetrafluoroborate

Chemical Property of [Cu(bis[2-(diphenylphosphino)phenyl]ether)₂]tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of [Cu(bis[2-(diphenylphosphino)phenyl]ether)₂]tetrafluoroborate

There total 1 articles about [Cu(bis[2-(diphenylphosphino)phenyl]ether)₂]tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

tetrakis(acetonitrile)copper(I)tetrafluoroborate + bis[2-(diphenylphosphino)phenyl] ether (166330-10-5) → [Cu(bis[2-(diphenylphosphino)phenyl]ether)2]tetrafluoroborate (947372-37-4)

Guidance literature:

In dichloromethane; under N2; soln. of Cu complex in CH2Cl2 added dropwise to stirred soln. of ligand in CH2Cl2 at room temp.; 8 h; concd.; Et2O added; crystd. at room temp. for 1 d; elem. anal.;

DOI:10.1021/ic7005474

Reference yield: 87.0%

manganese(IV) oxide (1313-13-9) + [Cu(bis[2-(diphenylphosphino)phenyl]ether)2]tetrafluoroborate (947372-37-4) → [Cu(κ2-P,P'-bis(2-(diphenylphosphino)phenyl) ether)(κ2-P,O-Ph2PC6H4OC6H4P(O)Ph2)][BF4] (947372-39-6)

Guidance literature:

In dichloromethane; under N2; mixt. of Cu complex and MnO2 in CH2Cl2 stirred at room temp. for 2 h; filtered; concd.; Et2O added; crystals collected; elem. anal.;

DOI:10.1021/ic7005474

Reference yield: 82.0%

selenium (7782-49-2) + [Cu(bis[2-(diphenylphosphino)phenyl]ether)2]tetrafluoroborate (947372-37-4) → [Cu(κ2-P,P'-bis(2-(diphenylphosphino)phenyl) ether)(κ2-P,Se-Ph2PC6H4OC6H4P(Se)Ph2)][BF4] (947372-43-2)

Guidance literature:

In dichloromethane; under N2; mixt. of Cu complex and Se in CH2Cl2 stirred at room temp. for24 h; filtered; filtrate concd.; Et2O added; crystals collected; elem. anal.;

DOI:10.1021/ic7005474

upstream raw materials:

bis[2-(diphenylphosphino)phenyl] ether

Downstream raw materials:

[Cu(κ2-P,P'-bis(2-(diphenylphosphino)phenyl) ether)(κ2-P,S-Ph2PC6H4OC6H4P(S)Ph2)][BF4]

[Cu(κ2-P,P'-bis(2-(diphenylphosphino)phenyl) ether)(κ2-P,O-Ph2PC6H4OC6H4P(O)Ph2)][BF4]

[Cu(κ2-P,P'-bis(2-(diphenylphosphino)phenyl) ether)(κ2-P,Se-Ph2PC6H4OC6H4P(Se)Ph2)][BF4]