Technology Process of C34H38O6
There total 5 articles about C34H38O6 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C31H32O7; allyl-trimethyl-silane;
With
trimethylsilyl trifluoromethanesulfonate;
In
dichloromethane;
at -78 ℃;
for 0.0833333h;
With
Wilkinson's catalyst; hydrogen;
In
ethanol;
at 20 ℃;
for 1h;
stereoselective reaction;
DOI:10.1016/j.tetlet.2010.12.061
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: diisobutylaluminium hydride / toluene / 2 h / -78 °C
2.1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 0.08 h / -78 °C
2.2: 1 h / 20 °C
With
trimethylsilyl trifluoromethanesulfonate; diisobutylaluminium hydride;
In
dichloromethane; toluene;
DOI:10.1016/j.tetlet.2010.12.061
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: lithium hexamethyldisilazane / tetrahydrofuran / 0.17 h / -78 °C
1.2: -78 - 20 °C
1.3: 0.08 h / -15 °C
2.1: 18-crown-6 ether; potassium carbonate / acetone / 4 h / Reflux
3.1: diisobutylaluminium hydride / toluene / 2 h / -78 °C
4.1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 0.08 h / -78 °C
4.2: 1 h / 20 °C
With
18-crown-6 ether; trimethylsilyl trifluoromethanesulfonate; diisobutylaluminium hydride; potassium carbonate; lithium hexamethyldisilazane;
In
tetrahydrofuran; dichloromethane; acetone; toluene;
1.1: Michael-Dieckmann type cyclization / 1.2: Michael-Dieckmann type cyclization / 1.3: Michael-Dieckmann type cyclization;
DOI:10.1016/j.tetlet.2010.12.061
