2((C₆H₅)3P)2N⁽¹⁺⁾*Ni₉(CO)18^(2-)=(((C₆H₅)3P)2N)2(Ni₉(CO)18)

Base Information

• Chemical Name: 2((C₆H₅)3P)2N⁽¹⁺⁾*Ni₉(CO)18^(2-)=(((C₆H₅)3P)2N)2(Ni₉(CO)18)
• CAS No.: 60512-59-6
• Molecular Formula: C₁₈Ni₉O₁₈*2C₃₆H₃₀NP₂
• Molecular Weight: 2109.57
• Mol file: 60512-59-6.mol

Synonyms:2((C₆H₅)3P)2N⁽¹⁺⁾*Ni₉(CO)18^(2-)=(((C₆H₅)3P)2N)2(Ni₉(CO)18)

Chemical Property of 2((C₆H₅)3P)2N⁽¹⁺⁾*Ni₉(CO)18^(2-)=(((C₆H₅)3P)2N)2(Ni₉(CO)18)

Chemical Property:

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Technology Process of 2((C₆H₅)3P)2N⁽¹⁺⁾*Ni₉(CO)18^(2-)=(((C₆H₅)3P)2N)2(Ni₉(CO)18)

There total 3 articles about 2((C₆H₅)3P)2N⁽¹⁺⁾*Ni₉(CO)18^(2-)=(((C₆H₅)3P)2N)2(Ni₉(CO)18) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

bis(triphenylphosphoranylidene)ammonium borohydride (65013-26-5) + tetracarbonyl nickel (13463-39-3,71564-36-8) → 2((C6H5)3P)2N(1+)*Ni9(CO)18(2-)=(((C6H5)3P)2N)2(Ni9(CO)18) (60512-59-6)

Guidance literature:

In dichloromethane; under inert atmosphere, Ni(CO)4 condenced into soln. of (PPN)BH4 (molarratio 4.5:1) in CH2Cl2, warmed to ambient temp., refluxed for 4 h; filtered on Celite, ether added to filtrate, stood overnight at -10°C; elem. anal.;

DOI:10.1021/ic50226a085

Reference yield: 50.0%

(Ppn)2W2(CO)10 Ppn + tetracarbonyl nickel (13463-39-3,71564-36-8) → 2((C6H5)3P)2N(1+)*Ni9(CO)18(2-)=(((C6H5)3P)2N)2(Ni9(CO)18) (60512-59-6)

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); under inert atmosphere, soln. of W- complex and Ni(CO)4 (molar ratio 1:10) in THF refluxed for 4 h;

DOI:10.1021/ic50226a085

Reference yield: 45.0%

2{N(P(C6H5)3)2}(1+)*{Ni3W2(CO)16}(2-)={N(P(C6H5)3)2}2{Ni3W2(CO)16} + tetracarbonyl nickel (13463-39-3,71564-36-8) → 2((C6H5)3P)2N(1+)*Ni9(CO)18(2-)=(((C6H5)3P)2N)2(Ni9(CO)18) (60512-59-6)

Guidance literature:

In tetrahydrofuran; under inert atmosphere, mixt. of Ni-W-complex and Ni(CO)4 (molar ratio 1:10) in THF refluxed for 4 h; filtered on Celite, ether added to filtrate, stood overnight at -10°C; monitored by IR spectra;

DOI:10.1021/ic50226a085

upstream raw materials:

tetracarbonyl nickel

bis(triphenylphosphoranylidene)ammonium borohydride