trans-<3-²H>allyl alcohol

Base Information

• Chemical Name: trans-<3-²H>allyl alcohol
• CAS No.: 78370-38-4
• Molecular Formula: C₃H₆O
• Molecular Weight: 59.0721
• Mol file: 78370-38-4.mol

Synonyms:trans-<3-²H>allyl alcohol

Chemical Property of trans-<3-²H>allyl alcohol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-<3-²H>allyl alcohol

There total 3 articles about trans-<3-²H>allyl alcohol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

propargyl alcohol (107-19-7) → Z-<3-2H>-allyl alcohol (78370-38-4,116546-11-3,78370-35-1) + allyl alcohol (107-18-6)

Guidance literature:

propargyl alcohol; With lithium aluminium tetrahydride; In diethyl ether; at 35 ℃; for 24h;

With water-d2; stereoselective reaction;

DOI:10.1021/ol301212j

Reference yield:

3,O-dideuterioprop-2-yn-1-ol (19417-24-4) → trans-<3-2H>allyl alcohol (78370-38-4) + cis-<3-2H>allyl alcohol (142745-16-2) + allyl alcohol (107-18-6)

Guidance literature:

With lithium aluminium tetrahydride; water-d2; Yield given. Multistep reaction; 1.) ether;

DOI:10.1021/ja00405a032

Reference yield:

propargyl alcohol (107-19-7) → 2,2-dideuterio-propan-1-ol (40422-14-8) + <2-2H>-allyl alcohol (20965-32-6) + trans-<3-2H>allyl alcohol (78370-38-4)

Guidance literature:

With lithium aluminium deuteride; In diethyl ether; for 18h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Heating;

upstream raw materials:

propargyl alcohol

3,O-dideuterioprop-2-yn-1-ol

Downstream raw materials:

(Z)-3-(2-Propenoxy)cyclohex-2-en-1-one-d1

(E)-3-(2-Propenoxy)cyclohex-2-en-1-one-d1

E-[3-²H]-propenyl benzoate

C₁₁H₁₂⁽²⁾HNO₄S