cis-Rh{Ph₂P(CH₂)3PPh₂}(COCH₃)(I)2

Base Information

Chemical Name:cis-Rh{Ph₂P(CH₂)3PPh₂}(COCH₃)(I)2
CAS No.:122924-33-8
Molecular Formula:C₂₉H₂₉I₂OP₂Rh
Molecular Weight:812.211
Hs Code.:

cis-Rh{Ph<sub>2</sub>P(CH<sub>2</sub>)3PPh<sub>2</sub>}(COCH<sub>3</sub>)(I)2

Synonyms:cis-Rh{Ph₂P(CH₂)3PPh₂}(COCH₃)(I)2

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Chemical Property of cis-Rh{Ph₂P(CH₂)3PPh₂}(COCH₃)(I)2

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Technology Process of cis-Rh{Ph₂P(CH₂)3PPh₂}(COCH₃)(I)2

There total 4 articles about cis-Rh{Ph₂P(CH₂)3PPh₂}(COCH₃)(I)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: acetylacetonatodicarbonylrhodium(l)

: 6737-42-4
1,3-bis-(diphenylphosphino)propane

: 122924-33-8
cis-Rh{Ph₂P(CH₂)3PPh₂}(COCH₃)(I)2

Guidance literature:: With carbon monoxide; hydrogen; methyl iodide; In methanol; minireactor, N2-atmosphere; pressuring to 400psig with CO/H2; heating to 140°C; pressuring to 750 psig (1.5 h); cooling to 15°C; analysis;
DOI:10.1021/om00114a025

Reference yield: 79.0%

: 122924-38-3
Rh{(C₆H₅)2P(CH₂)3P(C₆H₅)2}HI₂

: 122924-33-8
cis-Rh{Ph₂P(CH₂)3PPh₂}(COCH₃)(I)2

Guidance literature:: With carbon monoxide; In methanol; Fisher-Porter bottle, under protective gas; pressuring/venturing 3 times with 125 psig CO; pressuring with 100 psig CO, lowering into 100°C oil bath (45 min); cooling; filtration; washing (CH3OH); drying in vacuum;
DOI:10.1021/om00114a025

Reference yield: 78.0%

: 756480-18-9
[rhodium(III)diiodide(acetyl)(carbonyl)(NCMe)]2

: 6737-42-4
1,3-bis-(diphenylphosphino)propane

: 122924-33-8
[Rh(dppp)(COMe)I₂]

Guidance literature:: In dichloromethane; dppp and Rh complex were dissolved in CH2Cl2 and warmed to gentle refluxfor 1 h; Et2O was added, 24 h at -10°C, ppt. was filtered; elem. anal.;
DOI:10.1016/j.ica.2004.03.018