triethylammonium 1-O-(6-(S-benzyl)thiohexylphosphonato)-2-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-3,4,5,6-tetra-O-benzyl-D-myo-inositol

Base Information

• Chemical Name: triethylammonium 1-O-(6-(S-benzyl)thiohexylphosphonato)-2-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-3,4,5,6-tetra-O-benzyl-D-myo-inositol
• CAS No.: 1092959-36-8
• Molecular Formula: C₆H₁₅N*C₈₁H₈₉O₁₄PS
• Molecular Weight: 1450.82
• Mol file: 1092959-36-8.mol

Synonyms:triethylammonium 1-O-(6-(S-benzyl)thiohexylphosphonato)-2-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-3,4,5,6-tetra-O-benzyl-D-myo-inositol

Chemical Property of triethylammonium 1-O-(6-(S-benzyl)thiohexylphosphonato)-2-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-3,4,5,6-tetra-O-benzyl-D-myo-inositol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of triethylammonium 1-O-(6-(S-benzyl)thiohexylphosphonato)-2-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-3,4,5,6-tetra-O-benzyl-D-myo-inositol

There total 2 articles about triethylammonium 1-O-(6-(S-benzyl)thiohexylphosphonato)-2-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-3,4,5,6-tetra-O-benzyl-D-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

→ triethylammonium 1-O-(6-(S-benzyl)thiohexylphosphonato)-2-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-3,4,5,6-tetra-O-benzyl-D-myo-inositol (1092959-36-8)

Guidance literature:

Reference yield: 88.0%

triethylammonium 6-(benzylthio)hexylphosphonate + 3,4,5,6-tetra-O-benzyl-2-O-(2',3',4',6'-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol (124684-96-4) → triethylammonium 1-O-(6-(S-benzyl)thiohexylphosphonato)-2-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-3,4,5,6-tetra-O-benzyl-D-myo-inositol (1092959-36-8)

Guidance literature:

triethylammonium 6-(benzylthio)hexylphosphonate; 3,4,5,6-tetra-O-benzyl-2-O-(2',3',4',6'-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol; With pivaloyl chloride; In pyridine; at 20 ℃; for 3h; Inert atmosphere;

With iodine; In pyridine; water; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1021/ja806283e

Reference yield: 43.0%

triethylammonium 1-O-(6-(S-benzyl)thiohexylphosphonato)-2-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-3,4,5,6-tetra-O-benzyl-D-myo-inositol (1092959-36-8) → PIM1 (1092959-20-0)

Guidance literature:

triethylammonium 1-O-(6-(S-benzyl)thiohexylphosphonato)-2-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-3,4,5,6-tetra-O-benzyl-D-myo-inositol; With ammonia; sodium; In tetrahydrofuran; tert-butyl alcohol; at -78 ℃; for 0.5h; Inert atmosphere;

With methanol; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1021/ja806283e

upstream raw materials:

3,4,5,6-tetra-O-benzyl-2-O-(2',3',4',6'-tetra-O-benzyl-α-D-mannopyranosyl)-D-myo-inositol

Downstream raw materials:

PIM₁