methyl 2-acetamido-3-O-benzoyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

Base Information

• Chemical Name: methyl 2-acetamido-3-O-benzoyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside
• CAS No.: 496065-66-8
• Molecular Formula: C₂₃H₂₅NO₇
• Molecular Weight: 427.454
• Mol file: 496065-66-8.mol

Synonyms:methyl 2-acetamido-3-O-benzoyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

Chemical Property of methyl 2-acetamido-3-O-benzoyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 2-acetamido-3-O-benzoyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

There total 1 articles about methyl 2-acetamido-3-O-benzoyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

methyl 2-acetylamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside (87038-18-4) + benzoyl chloride (98-88-4) → methyl 2-acetamido-3-O-benzoyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside (496065-66-8)

Guidance literature:

With pyridine; In dichloromethane; at 20 ℃; for 5h;

DOI:10.1139/v02-117

Reference yield: 95.0%

methyl 2-acetamido-3-O-benzoyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside (496065-66-8) → methyl 2-acetamido-3-O-benzoyl-6-O-benzyl-2-deoxy-β-D-glucopyranoside (496065-67-9)

Guidance literature:

With hydrogenchloride; 4 A molecular sieve; sodium cyanoborohydride; methyl orange; In tetrahydrofuran; diethyl ether; for 2h;

DOI:10.1139/v02-117

Reference yield: 38.0%

methyl 2-acetamido-3-O-benzoyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside (496065-66-8) → methyl 2-acetamido-3,6-di-O-benzoyl-2-deoxy-β-D-glucopyranoside (176690-90-7) + methyl 2-acetamido-3,4-di-O-benzoyl-2-deoxy-β-D-glucopyranoside

Guidance literature:

With 3,3-dimethyldioxirane; In acetone; at 5 ℃; for 96h; Inert atmosphere;

DOI:10.1021/jo9026098

upstream raw materials:

methyl 2-acetylamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

benzoyl chloride

Downstream raw materials:

methyl 2-acetamido-3-O-benzoyl-6-O-benzyl-2-deoxy-β-D-glucopyranoside

methyl 2-acetamido-6-O-benzyl-2,4-dideoxy-β-D-xylo-hexopyranoside

methyl 2-acetamido-3-O-benzoyl-6-O-benzyl-2,4-dideoxy-β-D-xylo-hexopyranoside

methyl 2-acetamido-3-O-benzoyl-6-O-benzyl-2-deoxy-4-(imidazol-1-yl)thiocarbonyl-β-D-glucopyranoside