C₃₂H₄₄BNO₆Si

Base Information

• Chemical Name: C₃₂H₄₄BNO₆Si
• CAS No.: 1425052-07-8
• Molecular Formula: C₃₂H₄₄BNO₆Si
• Molecular Weight: 577.601
• Mol file: 1425052-07-8.mol

Synonyms:C₃₂H₄₄BNO₆Si

Chemical Property of C₃₂H₄₄BNO₆Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₂H₄₄BNO₆Si

There total 7 articles about C₃₂H₄₄BNO₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2‐methoxy‐4‐(4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolan‐2‐yl)phenyl)methanol (1404094-91-2) + C18H24O3Si (1425051-92-8) → C32H44BNO6Si (1425052-07-8)

Guidance literature:

C₁₈H₂₄O₃Si; With diphenylphosphoranyl azide; triethylamine; In benzene; at 85 ℃; for 1h; Inert atmosphere;

(2‐methoxy‐4‐(4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolan‐2‐yl)phenyl)methanol; In benzene; at 85 ℃; for 3h; Inert atmosphere;

DOI:10.1021/jo400105m

Reference yield:

bis(pinacol)diborane (73183-34-3) → C32H44BNO6Si (1425052-07-8)

Guidance literature:

Multi-step reaction with 2 steps

1.1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; 1,1'-bis-(diphenylphosphino)ferrocene; potassium acetate / 1,4-dioxane / 48 h / 80 °C / Inert atmosphere

2.1: diphenylphosphoranyl azide; triethylamine / benzene / 1 h / 85 °C / Inert atmosphere

2.2: 3 h / 85 °C / Inert atmosphere

With 1,1'-bis-(diphenylphosphino)ferrocene; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; diphenylphosphoranyl azide; potassium acetate; triethylamine; In 1,4-dioxane; benzene; 1.1: |Miyaura Borylation Reaction / 2.1: |Curtius Rearrangement / 2.2: |Curtius Rearrangement;

DOI:10.1021/jo400105m

Reference yield:

C17H23BrOSi (1425052-05-6) → C32H44BNO6Si (1425052-07-8)

Guidance literature:

Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 0.08 h / -78 °C / Inert atmosphere

1.2: 1.5 h / -78 - 23 °C / Inert atmosphere

2.1: sodium dihydrogen phosphate monohydrate; sodium chlorite; 2-methyl-but-2-ene / water; acetone / 0.5 h / 23 °C / Inert atmosphere

3.1: diphenylphosphoranyl azide; triethylamine / benzene / 1 h / 85 °C / Inert atmosphere

3.2: 3 h / 85 °C / Inert atmosphere

With sodium chlorite; n-butyllithium; sodium dihydrogen phosphate monohydrate; 2-methyl-but-2-ene; diphenylphosphoranyl azide; triethylamine; In tetrahydrofuran; hexane; water; acetone; benzene; 3.1: |Curtius Rearrangement / 3.2: |Curtius Rearrangement;

DOI:10.1021/jo400105m

upstream raw materials:

bis(pinacol)diborane

(2‐methoxy‐4‐(4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolan‐2‐yl)phenyl)methanol

C₁₈H₂₄O₃Si

1-bromo-4-bromomethyl-naphthalene

Downstream raw materials:

C₂₆H₃₀BNO₆

C₃₃H₃₄BN₃O₉