(E)-3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl acetate

Base Information

Chemical Name:(E)-3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl acetate
CAS No.:152125-17-2
Molecular Formula:C₂₀H₃₆O₃Si
Molecular Weight:352.59
Hs Code.:

Synonyms:(E)-3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl acetate

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Chemical Property of (E)-3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl acetate

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Technology Process of (E)-3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl acetate

There total 6 articles about (E)-3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 20548-02-1
trans (4R,6R)-4-hydroxy-2,2,6-trimethylcyclohexanone

: 152125-17-2
(E)-3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl acetate

Guidance literature:: Multi-step reaction with 5 steps

1: 93 percent / Et₃N, 4-dimethylaminopyridine / CH₂Cl₂ / 2 h / Ambient temperature

2: 1) iPr₂NLi / 1) THF, hexane, 1 h, -78 deg C, 2) THF, 5 h, 0 deg C

3: 93 percent / Et₃N / PdCl₂(Ph₃P)2 / dimethylformamide / 22 h / 75 °C

4: LiAlH₄ / diethyl ether / 0.5 h / 0 °C

5: pyridine / 16 h / Ambient temperature

With pyridine; dmap; lithium aluminium tetrahydride; triethylamine; lithium diisopropyl amide; bis-triphenylphosphine-palladium(II) chloride; In diethyl ether; dichloromethane; N,N-dimethyl-formamide;

Reference yield:

: 146566-70-3
4-tert-Butyldimethylsilyloxy-2,2,6-trimethylcyclohexanone

: 152125-17-2
(E)-3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl acetate

Guidance literature:: Multi-step reaction with 4 steps

1: 1) iPr₂NLi / 1) THF, hexane, 1 h, -78 deg C, 2) THF, 5 h, 0 deg C

2: 93 percent / Et₃N / PdCl₂(Ph₃P)2 / dimethylformamide / 22 h / 75 °C

3: LiAlH₄ / diethyl ether / 0.5 h / 0 °C

4: pyridine / 16 h / Ambient temperature

With pyridine; lithium aluminium tetrahydride; triethylamine; lithium diisopropyl amide; bis-triphenylphosphine-palladium(II) chloride; In diethyl ether; N,N-dimethyl-formamide;

Reference yield:

: 146517-38-6
4-tert-Butyldimethylsilyloxy-2,2,6-trimethylcyclohex-1-enyl trifluoromethanesulfonate

: 152125-17-2
(E)-3-(4-tert-Butyldimethylsilyloxy-2,6,6-trimethylcyclohex-1-enyl)allyl acetate

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / Et₃N / PdCl₂(Ph₃P)2 / dimethylformamide / 22 h / 75 °C

2: LiAlH₄ / diethyl ether / 0.5 h / 0 °C

3: pyridine / 16 h / Ambient temperature

With pyridine; lithium aluminium tetrahydride; triethylamine; bis-triphenylphosphine-palladium(II) chloride; In diethyl ether; N,N-dimethyl-formamide;