(E)-methyl 2'-{[(perfluorophenyl)imino]methyl}-(1,1'-biphenyl)-4-carboxylate

Base Information

Chemical Name:(E)-methyl 2'-{[(perfluorophenyl)imino]methyl}-(1,1'-biphenyl)-4-carboxylate
CAS No.:1578265-98-1
Molecular Formula:C₂₁H₁₂F₅NO₂
Molecular Weight:405.324
Hs Code.:

Synonyms:(E)-methyl 2'-{[(perfluorophenyl)imino]methyl}-(1,1'-biphenyl)-4-carboxylate

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Chemical Property of (E)-methyl 2'-{[(perfluorophenyl)imino]methyl}-(1,1'-biphenyl)-4-carboxylate

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Technology Process of (E)-methyl 2'-{[(perfluorophenyl)imino]methyl}-(1,1'-biphenyl)-4-carboxylate

There total 4 articles about (E)-methyl 2'-{[(perfluorophenyl)imino]methyl}-(1,1'-biphenyl)-4-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 619-42-1
4-methoxycarbonylphenyl bromide

: 1578265-83-4
(E)-2,3,4,5,6-pentafluoro-N-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzylidene)aniline

: 1578265-98-1
(E)-methyl 2'-{[(perfluorophenyl)imino]methyl}-(1,1'-biphenyl)-4-carboxylate

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium phosphate; In 1,3,5-trimethyl-benzene; at 120 ℃; for 24h; Inert atmosphere;
DOI:10.1039/c3ob42497a

Reference yield:

: 143896-70-2
(E)-N-benzylidene-2,3,4,5,6-pentafluoroaniline

: 1578265-98-1
(E)-methyl 2'-{[(perfluorophenyl)imino]methyl}-(1,1'-biphenyl)-4-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; tris(pentafluorophenyl)phosphine / 1,3,5-trimethyl-benzene / 0.17 h / 20 °C / Inert atmosphere

1.2: 3 h / 120 °C / Inert atmosphere

2.1: potassium phosphate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / 1,3,5-trimethyl-benzene / 24 h / 120 °C / Inert atmosphere

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium phosphate; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; tris(pentafluorophenyl)phosphine; In 1,3,5-trimethyl-benzene; 2.1: |Suzuki-Miyaura Coupling;
DOI:10.1039/c3ob42497a

Reference yield:

: 100-52-7
benzaldehyde

: 1578265-98-1
(E)-methyl 2'-{[(perfluorophenyl)imino]methyl}-(1,1'-biphenyl)-4-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1.1: magnesium sulfate / tetrahydrofuran / 48 h / 55 °C / Inert atmosphere

2.1: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; tris(pentafluorophenyl)phosphine / 1,3,5-trimethyl-benzene / 0.17 h / 20 °C / Inert atmosphere

2.2: 3 h / 120 °C / Inert atmosphere

3.1: potassium phosphate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / 1,3,5-trimethyl-benzene / 24 h / 120 °C / Inert atmosphere

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium phosphate; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; magnesium sulfate; tris(pentafluorophenyl)phosphine; In tetrahydrofuran; 1,3,5-trimethyl-benzene; 3.1: |Suzuki-Miyaura Coupling;
DOI:10.1039/c3ob42497a