(3S,7S,8R,9S)-3-benzyloxymethyl-8,10-isopropylidenedioxy-7,9-dimethyldecan-4-one

Base Information

Chemical Name:(3S,7S,8R,9S)-3-benzyloxymethyl-8,10-isopropylidenedioxy-7,9-dimethyldecan-4-one
CAS No.:110653-52-6
Molecular Formula:C₂₃H₃₆O₄
Molecular Weight:376.536
Hs Code.:

Synonyms:(3S,7S,8R,9S)-3-benzyloxymethyl-8,10-isopropylidenedioxy-7,9-dimethyldecan-4-one

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Chemical Property of (3S,7S,8R,9S)-3-benzyloxymethyl-8,10-isopropylidenedioxy-7,9-dimethyldecan-4-one

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Technology Process of (3S,7S,8R,9S)-3-benzyloxymethyl-8,10-isopropylidenedioxy-7,9-dimethyldecan-4-one

There total 9 articles about (3S,7S,8R,9S)-3-benzyloxymethyl-8,10-isopropylidenedioxy-7,9-dimethyldecan-4-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: (3S,5E,7S,8S,9S)-3-benzyloxymethyl-8,10-isopropylidenedioxy-7,9-dimethyl-5-decen-4-one

: 110653-52-6
(3S,7S,8R,9S)-3-benzyloxymethyl-8,10-isopropylidenedioxy-7,9-dimethyldecan-4-one

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethyl acetate;
DOI:10.1248/cpb.37.1698

Reference yield:

: 81520-10-7
(2S,3S,4S)-5-Benzyloxy-2,4-dimethylpentan-1,3-diol

: 110653-52-6
(3S,7S,8R,9S)-3-benzyloxymethyl-8,10-isopropylidenedioxy-7,9-dimethyldecan-4-one

Guidance literature:: Multi-step reaction with 5 steps

1: CSA / acetone / 0.5 h / Ambient temperature

2: 96 percent / hydrogen / 10percent Pd/C / ethanol / 3.5 h / Ambient temperature

3: 1) (COCl)2, DMSO, 2) Et₃N / 1) CH₂Cl₂, -70 deg C, 30 min, 2) CH₂Cl₂, -70 to 0 deg C

4: 1) NaH / 1) DMF, 45 min, 0 deg C, 2) DMF, THF, 0 to 20 deg C

5: 94 percent / hydrogen / 10percent Pd/C / ethyl acetate

With oxalyl dichloride; camphor-10-sulfonic acid; hydrogen; sodium hydride; dimethyl sulfoxide; triethylamine; palladium on activated charcoal; In ethanol; ethyl acetate; acetone;
DOI:10.1248/cpb.37.1698

Reference yield:

: 115181-73-2
(2S,3R,4S)-3,5-isopropylidenedioxy-2,4-dimethylpentanol

: 110653-52-6
(3S,7S,8R,9S)-3-benzyloxymethyl-8,10-isopropylidenedioxy-7,9-dimethyldecan-4-one

Guidance literature:: Multi-step reaction with 3 steps

1: 1) (COCl)2, DMSO, 2) Et₃N / 1) CH₂Cl₂, -70 deg C, 30 min, 2) CH₂Cl₂, -70 to 0 deg C

2: 1) NaH / 1) DMF, 45 min, 0 deg C, 2) DMF, THF, 0 to 20 deg C

3: 94 percent / hydrogen / 10percent Pd/C / ethyl acetate

With oxalyl dichloride; hydrogen; sodium hydride; dimethyl sulfoxide; triethylamine; palladium on activated charcoal; In ethyl acetate;
DOI:10.1248/cpb.37.1698