81520-10-7Relevant articles and documents
Synthesis of polypropionate subunits from cyclopropanes
Defosseux, Magali,Blanchard, Nicolas,Meyer, Christophe,Cossy, Janine
, p. 7632 - 7653 (2007/10/03)
The oxymercuration-reductive demercuration of several cyclopropanealkanol or their derivatives bearing adjacent stereocenters has been investigated in order to synthesize polypropionate subunits. The crucial importance of the ester protecting group for th
Synthesis of stereotriads by oxymercuration of substituted cyclopropylcarbinols.
Cossy,Blanchard,Meyer
, p. 2567 - 2569 (2007/10/03)
[structure: see text] Cyclopropylcarbinol derivatives bearing an adjacent methyl-substituted stereocenter and a remote beta-hydroxy group protected as a pivalate underwent anchimerically assisted regio- and diastereoselective oxymercurations, affording af
Stereoselective Total Synthesis of (+/-)-Invictolide. An Efficient Preparation of a Trisubstituted δ-Lactone from Aldol Precursors
Pilli, Ronaldo Aloise,Murta, Maria Marcia
, p. 338 - 342 (2007/10/02)
The stereoselective total synthesis of (+/-)-invictolide (1), a component of the queen recognition pheromone of Solenopsis invicta, is described.The TiCl4-mediated addition of silyl ketene thioacetal 8 to (+/-)-3-(benzyloxy)-2-methylpropionaldehyde afford