tolyl (R)-2-(tert-butoxycarbonylamino)-1-diazo-2-(3,4-(methylenedioxy)phenyl)ethylsulfone

Base Information

• Chemical Name: tolyl (R)-2-(tert-butoxycarbonylamino)-1-diazo-2-(3,4-(methylenedioxy)phenyl)ethylsulfone
• CAS No.: 1314115-28-0
• Molecular Formula: C₂₁H₂₃N₃O₆S
• Molecular Weight: 445.496
• Mol file: 1314115-28-0.mol

Synonyms:tolyl (R)-2-(tert-butoxycarbonylamino)-1-diazo-2-(3,4-(methylenedioxy)phenyl)ethylsulfone

Chemical Property of tolyl (R)-2-(tert-butoxycarbonylamino)-1-diazo-2-(3,4-(methylenedioxy)phenyl)ethylsulfone

Chemical Property:

Purity/Quality:

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Technology Process of tolyl (R)-2-(tert-butoxycarbonylamino)-1-diazo-2-(3,4-(methylenedioxy)phenyl)ethylsulfone

There total 1 articles about tolyl (R)-2-(tert-butoxycarbonylamino)-1-diazo-2-(3,4-(methylenedioxy)phenyl)ethylsulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

piperonal N-(tert-butoxycarbonyl)imine (890043-57-9) + p-tosyldiazomethane (1538-98-3) → tolyl (R)-2-(tert-butoxycarbonylamino)-1-diazo-2-(3,4-(methylenedioxy)phenyl)ethylsulfone (1314115-28-0)

Guidance literature:

With C₄₆H₄₆O₄; In dichloromethane; at 0 ℃; for 45h; optical yield given as %ee; enantioselective reaction; Molecular sieve;

DOI:10.1021/jo2005999

upstream raw materials:

piperonal N-(tert-butoxycarbonyl)imine

p-tosyldiazomethane