(tetrakis(2,4,6-triisopropylphenyl)porphyrinato)rhodium(II)

Base Information

• Chemical Name: (tetrakis(2,4,6-triisopropylphenyl)porphyrinato)rhodium(II)
• CAS No.: 138856-89-0
• Molecular Formula: C₈₀H₁₀₀N₄Rh
• Molecular Weight: 1220.61
• Mol file: 138856-89-0.mol

Synonyms:(tetrakis(2,4,6-triisopropylphenyl)porphyrinato)rhodium(II)

Chemical Property of (tetrakis(2,4,6-triisopropylphenyl)porphyrinato)rhodium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (tetrakis(2,4,6-triisopropylphenyl)porphyrinato)rhodium(II)

There total 1 articles about (tetrakis(2,4,6-triisopropylphenyl)porphyrinato)rhodium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{tetrakis(2,4,6-triisopropylphenyl)porphyrinato}methylrhodium → (tetrakis(2,4,6-triisopropylphenyl)porphyrinato)rhodium(II) (138856-89-0)

Guidance literature:

In benzene; Irradiation (UV/VIS); under Ar; benzene soln. of Rh complex was photolyzed in vacuum adapted NMR tube;

DOI:10.1139/v01-052

Reference yield:

(tetrakis(2,4,6-triisopropylphenyl)porphyrinato)rhodium(II) (138856-89-0) → (tetrakis(2,4,6-triisopropylphenyl)porphyrinato)rhodium(II)*carbon monoxide (138856-88-9)

Guidance literature:

With carbon monoxide; In toluene; exposure to CO (p > 100 Torr); detected by NMR;

DOI:10.1021/ja00031a022

Reference yield:

(tetrakis(2,4,6-triisopropylphenyl)porphyrinato)rhodium(II) (138856-89-0) + [13C]Carbon monoxide (1641-69-6) → (tetrakis(2,4,6-triisopropylphenyl)porphyrinato)rhodium(II)*(13)CO

Guidance literature:

In toluene; exposure to (13)CO; detected by ESR;

DOI:10.1021/ja00031a022

Downstream raw materials:

((C₄H₂NC(C₆H₂(CH(CH₃)2)3))4)Rh(CH₂CH₂)

(tetrakis(2,4,6-triisopropylphenyl)porphyrinato)rhodium(II)*carbon monoxide