(3aR,4R,6aS)-4-Benzyloxymethyl-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[1,3]dioxole

Base Information

Chemical Name:(3aR,4R,6aS)-4-Benzyloxymethyl-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[1,3]dioxole
CAS No.:869710-91-8
Molecular Formula:C₁₆H₂₀O₃
Molecular Weight:260.333
Hs Code.:

Synonyms:(3aR,4R,6aS)-4-Benzyloxymethyl-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[1,3]dioxole

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Chemical Property of (3aR,4R,6aS)-4-Benzyloxymethyl-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[1,3]dioxole

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Technology Process of (3aR,4R,6aS)-4-Benzyloxymethyl-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[1,3]dioxole

There total 34 articles about (3aR,4R,6aS)-4-Benzyloxymethyl-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[1,3]dioxole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 100-39-0
benzyl bromide

: 503303-03-5
(3S,4R,5R)-3,4-O-isopropylidene-5-hydroxymethylcyclopentene-3,4-diol

: 869710-91-8
(3aR,4R,6aS)-4-Benzyloxymethyl-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[1,3]dioxole

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2005.08.163

Reference yield: 80.0%

: (1R,2S,3R,4S)-2-(benzyloxymethyl)-3,4-(isopropylidenedioxy)cyclopentanol

: 87-42-3,111055-92-6
6-chloro-7H-purine

: 869710-91-8
(3aR,4R,6aS)-4-Benzyloxymethyl-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[1,3]dioxole

: 9-((3aR,4R,5S,6aS)-4-((benzyloxy)methyl)-2,2-dimethyltetrahydro-4H-cyclopenta[d][1,3]dioxol-5-yl)-6-chloro-9H-purine

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 20 ℃; Solvent; Micellar solution;
DOI:10.1055/s-0036-1591732

Reference yield: 70.0%

: 14631-20-0
4-N-Acetylcytosine

: (1R,2S,3R,4S)-2-(benzyloxymethyl)-3,4-(isopropylidenedioxy)cyclopentanol

: 869710-91-8
(3aR,4R,6aS)-4-Benzyloxymethyl-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[1,3]dioxole

: 2-(((3aR,4S,5S,6aS)-4-((benzyloxy)methyl)-2,2-dimethyltetrahydro-4H-cyclopenta[d][1,3]dioxol-5-yl)oxy)pyrimidin-4-amine

Guidance literature:: 4-N-Acetylcytosine; (1R,2S,3R,4S)-2-(benzyloxymethyl)-3,4-(isopropylidenedioxy)cyclopentanol; With di-isopropyl azodicarboxylate; triphenylphosphine; In acetonitrile; at 45 ℃; Microwave irradiation;

With sodium methylate; In methanol;
DOI:10.1055/s-0036-1591732