chloro[[dicarbonyl(η(5)-cyclopentadienyl)ferrio]methyl]methyl(phenyl)silane

Base Information

Chemical Name:chloro[[dicarbonyl(η(5)-cyclopentadienyl)ferrio]methyl]methyl(phenyl)silane
CAS No.:506406-19-5
Molecular Formula:C₁₅H₁₅ClFeO₂Si
Molecular Weight:346.668
Hs Code.:

Synonyms:chloro[[dicarbonyl(η(5)-cyclopentadienyl)ferrio]methyl]methyl(phenyl)silane

Suppliers and Price of chloro[[dicarbonyl(η(5)-cyclopentadienyl)ferrio]methyl]methyl(phenyl)silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of chloro[[dicarbonyl(η(5)-cyclopentadienyl)ferrio]methyl]methyl(phenyl)silane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of chloro[[dicarbonyl(η(5)-cyclopentadienyl)ferrio]methyl]methyl(phenyl)silane

There total 2 articles about chloro[[dicarbonyl(η(5)-cyclopentadienyl)ferrio]methyl]methyl(phenyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 669048-58-2
(η5-cyclopentadienyl)Fe(CO)2(Si(Me)(Ph)CH2Cl)

: 506406-19-5
chloro[[dicarbonyl(η(5)-cyclopentadienyl)ferrio]methyl]methyl(phenyl)silane

Guidance literature:: In benzene; in sealed NMR tube; thermolysis of Fe complex in benzene at 80°C; detd. by (29)Si and (13)C NMR spectra;
DOI:10.1021/ja030559+

Reference yield: 47.0%

: sodium dicarbonyl(cyclopentadienyl)ferrate

: 2632-83-9
chloro(chloromethyl)methyl(phenyl)silane

: 669048-58-2
(η5-cyclopentadienyl)Fe(CO)2(Si(Me)(Ph)CH2Cl)

: 506406-19-5
chloro[[dicarbonyl(η(5)-cyclopentadienyl)ferrio]methyl]methyl(phenyl)silane

Guidance literature:: In cyclohexane; byproducts: NaCl; under N2, stirring at room temp. for 36 h in the dark, mixt. was filtered, soln. was concd. in vac., distn. at 90 °C (E-2 Torr), resdue was heated at 120 °C for 3 h; SiCl-contg./CH2Cl-contg. isomer ratio was 80:20, mixt. was suspended in n-pentane (room temp.), soln. was filtered, concd., crystn. at -78°C, drying in vac., elem. anal.,;
DOI:10.1002/1099-0682(200212)2002:12<3242::AID-EJIC3242>3.0.CO;2-Q

Reference yield: 74.0%

: 506406-19-5
chloro[[dicarbonyl(η(5)-cyclopentadienyl)ferrio]methyl]methyl(phenyl)silane

: 7732-18-5
water

: 506406-38-8
[[dicarbonyl(η(5)-cyclopentadienyl)ferrio]methyl]methyl(phenyl)silanol

Guidance literature:: With Et₃N; In diethyl ether; water; byproducts: [Et3NH]Cl; under N2, Et3N in H2O was added to Et2O soln. of Fe-compd., stirring at room temp. for 4 h; ppt. and excess of H2O were removed by filtration via Na2SO4, filtrate was concd. in vac., treated with n-pentane, Fe-compds. were crystd. at 0 °C and filtered off, filtrate was concd., crystn. at -78 °C, drying in vac.;
DOI:10.1002/1099-0682(200212)2002:12<3242::AID-EJIC3242>3.0.CO;2-Q