methyl (E)-13-benzoyloxy-11-en-9-yn-octadecadienoate

Base Information

Chemical Name:methyl (E)-13-benzoyloxy-11-en-9-yn-octadecadienoate
CAS No.:96700-35-5
Molecular Formula:C₂₆H₃₆O₄
Molecular Weight:412.569
Hs Code.:

Synonyms:methyl (E)-13-benzoyloxy-11-en-9-yn-octadecadienoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (E)-13-benzoyloxy-11-en-9-yn-octadecadienoate

Chemical Property:

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Technology Process of methyl (E)-13-benzoyloxy-11-en-9-yn-octadecadienoate

There total 18 articles about methyl (E)-13-benzoyloxy-11-en-9-yn-octadecadienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 98-88-4
benzoyl chloride

: 98442-90-1
methyl (11E,13S)-13-hydroxyoctadec-11-en-9-ynoate

: 96700-35-5,98524-16-4
Benzoic acid (E)-(R)-12-methoxycarbonyl-1-pentyl-dodec-2-en-4-ynyl ester

Guidance literature:: With pyridine;

Reference yield:

: 19754-58-6
2-dec-9-ynyloxy-tetrahydro-pyran

: 96700-35-5
methyl (E)-13-benzoyloxy-11-en-9-yn-octadecadienoate

Guidance literature:: Multi-step reaction with 9 steps

1: 80 percent / CuCl, isopropyl amine, NH₂OH*HCl / methanol / 1 h

2: LAH / diethyl ether / 3 h / Ambient temperature

3: 89 percent / MnO₂ / CHCl₃ / 5 h / Ambient temperature

4: 1.) Mg / 1.) ether, r.t., 1 h; 2.) THF/ether, r.t., 1 h

5: 85 percent / pyridine / 6 h / Ambient temperature

6: 78 percent / PPTS / ethanol / 2 h / 55 °C

7: 75 percent / pyridinium dichromate / CH₂Cl₂ / 6 h / Ambient temperature

8: AgNO₃, KOH / ethanol; H₂O / 2 h / Ambient temperature

9: diethyl ether / 0.5 h / 0 °C

With pyridine; manganese(IV) oxide; potassium hydroxide; lithium aluminium tetrahydride; dipyridinium dichromate; hydroxylamine hydrochloride; pyridinium p-toluenesulfonate; silver nitrate; magnesium; isopropylamine; copper(l) chloride; In methanol; diethyl ether; ethanol; dichloromethane; chloroform; water;
DOI:10.1016/S0040-4020(01)87295-1

Reference yield:

: 17643-36-6
9-decyn-1-ol

: 96700-35-5
methyl (E)-13-benzoyloxy-11-en-9-yn-octadecadienoate

Guidance literature:: Multi-step reaction with 10 steps

1: 85 percent / p-TsOH / CH₂Cl₂ / 6 h / Ambient temperature

2: 80 percent / CuCl, isopropyl amine, NH₂OH*HCl / methanol / 1 h

3: LAH / diethyl ether / 3 h / Ambient temperature

4: 89 percent / MnO₂ / CHCl₃ / 5 h / Ambient temperature

5: 1.) Mg / 1.) ether, r.t., 1 h; 2.) THF/ether, r.t., 1 h

6: 85 percent / pyridine / 6 h / Ambient temperature

7: 78 percent / PPTS / ethanol / 2 h / 55 °C

8: 75 percent / pyridinium dichromate / CH₂Cl₂ / 6 h / Ambient temperature

9: AgNO₃, KOH / ethanol; H₂O / 2 h / Ambient temperature

10: diethyl ether / 0.5 h / 0 °C

With pyridine; manganese(IV) oxide; potassium hydroxide; lithium aluminium tetrahydride; dipyridinium dichromate; hydroxylamine hydrochloride; pyridinium p-toluenesulfonate; toluene-4-sulfonic acid; silver nitrate; magnesium; isopropylamine; copper(l) chloride; In methanol; diethyl ether; ethanol; dichloromethane; chloroform; water;
DOI:10.1016/S0040-4020(01)87295-1