acetic acid 3-[1-(4-methoxybenzyl)-but-2-enyloxy]-1-methylenenonyl ester

Base Information

Chemical Name:acetic acid 3-[1-(4-methoxybenzyl)-but-2-enyloxy]-1-methylenenonyl ester
CAS No.:791112-31-7
Molecular Formula:C₂₄H₃₆O₄
Molecular Weight:388.547
Hs Code.:

Synonyms:acetic acid 3-[1-(4-methoxybenzyl)-but-2-enyloxy]-1-methylenenonyl ester

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Chemical Property of acetic acid 3-[1-(4-methoxybenzyl)-but-2-enyloxy]-1-methylenenonyl ester

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Technology Process of acetic acid 3-[1-(4-methoxybenzyl)-but-2-enyloxy]-1-methylenenonyl ester

There total 6 articles about acetic acid 3-[1-(4-methoxybenzyl)-but-2-enyloxy]-1-methylenenonyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 64-19-7,77671-22-8
acetic acid

: 791112-30-6
1-methoxy-4-[2-(1-prop-2-ynylheptyloxy)-pent-3-enyl]benzene

: 791112-31-7
acetic acid 3-[1-(4-methoxybenzyl)-but-2-enyloxy]-1-methylenenonyl ester

Guidance literature:: With [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; trifuran-2-yl-phosphane; sodium carbonate; In benzene; at 80 ℃; for 15h;
DOI:10.1021/ja046125b

Reference yield:

: 111-71-7
heptanal

: 791112-31-7
acetic acid 3-[1-(4-methoxybenzyl)-but-2-enyloxy]-1-methylenenonyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 84 percent / p-TsOH / benzene / 15 h / Heating

2: 84 percent / TiCl₄ / CH₂Cl₂ / 0.25 h / -78 °C

3: NaHCO₃; Dess-Martin periodinane / CH₂Cl₂ / 1.5 h / 0 - 20 °C

4: 191.8 mg / KHMDS / 1,2-dimethoxy-ethane / 12 h / -60 °C

5: 42 percent / Na₂CO₃; [Ru(p-cymene)Cl₂]2; tri-(2-furyl)phosphine / benzene / 15 h / 80 °C

With [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; trifuran-2-yl-phosphane; titanium tetrachloride; potassium hexamethylsilazane; sodium hydrogencarbonate; sodium carbonate; Dess-Martin periodane; toluene-4-sulfonic acid; In 1,2-dimethoxyethane; dichloromethane; benzene;
DOI:10.1021/ja046125b

Reference yield:

: 127852-64-6
(S)-3-(4-methoxyphenyl)-1,2-propandiol

: 791112-31-7
acetic acid 3-[1-(4-methoxybenzyl)-but-2-enyloxy]-1-methylenenonyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 84 percent / p-TsOH / benzene / 15 h / Heating

2: 84 percent / TiCl₄ / CH₂Cl₂ / 0.25 h / -78 °C

3: NaHCO₃; Dess-Martin periodinane / CH₂Cl₂ / 1.5 h / 0 - 20 °C

4: 191.8 mg / KHMDS / 1,2-dimethoxy-ethane / 12 h / -60 °C

5: 42 percent / Na₂CO₃; [Ru(p-cymene)Cl₂]2; tri-(2-furyl)phosphine / benzene / 15 h / 80 °C

With [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; trifuran-2-yl-phosphane; titanium tetrachloride; potassium hexamethylsilazane; sodium hydrogencarbonate; sodium carbonate; Dess-Martin periodane; toluene-4-sulfonic acid; In 1,2-dimethoxyethane; dichloromethane; benzene;
DOI:10.1021/ja046125b