undecacarbonyl (tris(4-methylphenyl)phosphino) triruthenium

Base Information

Chemical Name:undecacarbonyl (tris(4-methylphenyl)phosphino) triruthenium
CAS No.:83343-69-5
Molecular Formula:C₃₂H₂₁O₁₁PRu₃
Molecular Weight:915.696
Hs Code.:

Synonyms:undecacarbonyl (tris(4-methylphenyl)phosphino) triruthenium

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Chemical Property of undecacarbonyl (tris(4-methylphenyl)phosphino) triruthenium

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Technology Process of undecacarbonyl (tris(4-methylphenyl)phosphino) triruthenium

There total 2 articles about undecacarbonyl (tris(4-methylphenyl)phosphino) triruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 1038-95-5,218281-19-7
Tri(p-tolyl)phosphine

: 83343-69-5
undecacarbonyl (tris(4-methylphenyl)phosphino) triruthenium

Guidance literature:: With sodium diphenylketyl; In tetrahydrofuran; a THF soln. of Ph2CONa was added dropwise under N2 to a soln. of Ru3(CO)12 and (p-Tol)3P in 1:1 molar ratio in THF, reaction was monitored by IR spectroscopy; THF was pumped off under vac., residue recrystd.; elem. anal.;
DOI:10.1016/0022-328X(83)85174-2

Reference yield: 22.0%

: 69403-55-0,89397-37-5
Ru₃(carbonyl)11(t-butyl isocyanide)

: 1038-95-5,218281-19-7
Tri(p-tolyl)phosphine

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 83343-69-5
undecacarbonyl (tris(4-methylphenyl)phosphino) triruthenium

Guidance literature:: In Petroleum ether; under N2; mixt. is heated in refluxing light petroleum for 30 min; chromy. (Florisil);

Reference yield: 10.0%

: 83343-69-5
undecacarbonyl (tris(4-methylphenyl)phosphino) triruthenium

: {Ru4(CO)11(μ4-PC6H4-p-Me)(μ4-η4-C6H3-4-Me)}

: {Ru3(CO)7(μ-P(C6H4-p-Me)2)2(μ3-η2-C6H3-4-Me)}

Guidance literature:: In toluene; byproducts: {Ru3(CO)12}; under dinitrogen; refluxed for 2.5 h; solvent was removed under reduced pressure; chromy. (alumina); elution (hexane/CH2Cl2=20:1); 1. band: (Ru3(CO)12); 2. band: Ru3-complex; 3. band: Ru4-complex; elem. anal.; NMR; IR;
DOI:10.1016/0022-328X(90)87246-A