CpFe(CO)2(κSe-SeCS2Ph)

Base Information

Chemical Name:CpFe(CO)2(κSe-SeCS2Ph)
CAS No.:952296-95-6
Molecular Formula:C₁₄H₁₀FeO₂S₂Se
Molecular Weight:409.171
Hs Code.:

Synonyms:CpFe(CO)2(κSe-SeCS2Ph)

Suppliers and Price of CpFe(CO)2(κSe-SeCS2Ph)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of CpFe(CO)2(κSe-SeCS2Ph)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of CpFe(CO)2(κSe-SeCS2Ph)

There total 1 articles about CpFe(CO)2(κSe-SeCS2Ph) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 16911-89-0
phenyl chlorodithioformate

: ((η5-C5H5)Fe(CO)2)2Se

: 952296-95-6
CpFe(CO)2(κSe-SeCS2Ph)

Guidance literature:: In diethyl ether; byproducts: C5H5Fe(CO)2Cl; (Ar); 1.2 equiv. of Et2O soln. of organic ligand added dropwise to Fe-compound in Et2O; stirred for 2 h under protection of light; stripped to dryness; redissolved in CH2Cl2; introduced to silica gel column made up in hexane; eluted with hexane; eluted with Et2O:hexane 1:1 ratio; recrystallized from CH2Cl2/hexane; elem. anal.;
DOI:10.1016/j.poly.2007.04.010

Reference yield: 81.0%

: 952296-95-6
CpFe(CO)2(κSe-SeCS2Ph)

: 603-35-0
triphenylphosphine

: CpFe(CO)(PPh₃)SeC(S)SC₆H₅

Guidance literature:: In tetrahydrofuran; at 0 ℃; Inert atmosphere; Schlenk technique; UV-irradiation;
DOI:10.1016/j.ica.2018.09.063

Reference yield: 78.0%

: 952296-95-6
CpFe(CO)2(κSe-SeCS2Ph)

: 952296-98-9
CpFe(CO)(κ2S,Se-SeCS2Ph)

Guidance literature:: In tetrahydrofuran; byproducts: CO; Irradiation (UV/VIS); THF soln. of Fe-complex irradiated under N2 for 15 min; volatiles removed in vacuum; purified by column chromy. using silica gelcolumn; eluted with CH2Cl2/hexane 1:5 mixt.; recrystallized by slow eva pn. of hexane soln.; elem. anal.;
DOI:10.1016/j.poly.2007.04.010