1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoate

Base Information

• Chemical Name: 1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoate
• CAS No.: 69901-42-4
• Molecular Formula: C₃₃H₅₀O₅
• Molecular Weight: 526.757
• Mol file: 69901-42-4.mol

Synonyms:1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoate

Chemical Property of 1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoate

There total 2 articles about 1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

2,4,6-tri-tert-butyl-4-hydroperoxycyclohexa-2,5-dienone (33919-05-0) + 3,5-di-tert-butyl-4-hydroxybenzoyl chloride (40056-43-7) → 1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoate (69901-42-4)

Guidance literature:

With pyridine; In Petroleum ether; at -20 ℃; for 1h;

DOI:10.1021/jo00169a017

Reference yield:

→ 1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoate (69901-42-4)

Guidance literature:

1-Alkyl-3.5-di-tert.-butyl-4-oxo-2.5-cyclohexadienylhydroperoxid, 3,5-Di-tert.-butyl-4-hydroxybenzylchlorid (durch Schotten-Baumann-Acylierung);

DOI:10.1016/S0040-4039(01)94993-7

Reference yield:

1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoate (69901-42-4) → 2,6-Di-tert-butyl-1,4-benzoquinone (719-22-2) + 3,5,3',5'-tetra-tert-butyl-4,4'-diphenoquinone (2455-14-3,74978-25-9) + 3,5-Di-tert-butyl-4-hydroxybenzoic acid (1421-49-4) + 2,4,6-tri-tert-butyl-4-tert-butoxy-2,5-cyclohexadienone (69217-39-6)

Guidance literature:

With manganese(IV) oxide; In benzene; at 0 - 10 ℃; for 2.5h; Mechanism; Product distribution; var. oxyd. reagent, var. solv., var. temp., var. time;

DOI:10.1021/jo00169a017

upstream raw materials:

2,4,6-tri-tert-butyl-4-hydroperoxycyclohexa-2,5-dienone

3,5-di-tert-butyl-4-hydroxybenzoyl chloride

Downstream raw materials:

2,6-Di-tert-butyl-1,4-benzoquinone

2,4,6-tri-tert-butylphenoxol

2,4,6-tri-tert-butyl-4-hydroxy-2,5-cyclohexadienone

3,5-Di-tert-butyl-4-hydroxybenzoic acid