33919-05-0

Basic information

• Product Name: 2,5-Cyclohexadien-1-one, 2,4,6-tris(1,1-dimethylethyl)-4-hydroperoxy-
• Synonyms: 2,4,6-tri-tert-butyl-4-hydroperoxy-cyclohexa-2,5-dienone
• CAS NO: 33919-05-0
• Molecular Formula: C18H30O3
• Molecular Weight: 294.434
• Mol File: 33919-05-0.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 393.5±42.0 °C(Predicted)
• Density: 0.99±0.1 g/cm3(Predicted)
• CAS DataBase Reference: 2,5-Cyclohexadien-1-one, 2,4,6-tris(1,1-dimethylethyl)-4-hydroperoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-Cyclohexadien-1-one, 2,4,6-tris(1,1-dimethylethyl)-4-hydroperoxy-(33919-05-0)
• EPA Substance Registry System: 2,5-Cyclohexadien-1-one, 2,4,6-tris(1,1-dimethylethyl)-4-hydroperoxy-(33919-05-0)

Safety Data

• Hazardous Substances Data: 33919-05-0(Hazardous Substances Data)

Upstream product

• 732-26-3 2,4,6-tri-tert-butylphenoxol 
• 3315-32-0 2,4,6-tri-tert-butylphenoxyl 

Downstream Products

• 4971-61-3 2,4,6-tri-tert-butyl-4-hydroxy-2,5-cyclohexadienone 
• 69901-42-4 1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl 3,5-di-tert-butyl-4-hydroxyperbenzoate 
• 719-22-2 2,6-Di-tert-butyl-1,4-benzoquinone 
• 13154-58-0 2,4,6-tri-tert-butyl-4-tert-butylperoxy-cyclohexa-2,5-dienone 
• 69217-39-6 2,4,6-tri-tert-butyl-4-tert-butoxy-2,5-cyclohexadienone 
• 62926-74-3 Ethaneperoxoic acid 1,3,5-tri-tert-butyl-4-oxo-cyclohexa-2,5-dienyl ester 
• 1975-14-0 2,4,6,2',4',6'-hexa-tert-butyl-4,4'-peroxy-bis-cyclohexa-2,5-dienone 
• 53539-63-2 C₆H₂(C(CH₃)3)3OOOCo(NCHC₆H₄O)2(CH₂)3NH(CH₂)3 

Relevant articles and documents

Catalytic oxidation of a trialkyl-substituted phenol and aniline with biomimetic schiff base complexes

The catalytic oxidation of 2,4,6-tri-tert-butylphenol and 2,4,6-tri-tert-butylaniline with molecular oxygen and tert-butylhydroperoxide was investigated using biomimetic Mn-, Fe- and Co-complexes as catalysts. The catalytic activity and product distribution were determined and compared with those observed in the reactions of the well-known Co(salen) complex.

PHOTOINDUCED ELECTRON TRANSFER OXIDATION - 1. 9,10-DICYANOANTHRACENE-SENSITIZED PHOTOOXIDATION OF HINDERED PHENOLS.

9,10-Dicyanoanthracene (DCA)-sensitized photooxidation reactions of hindered phenols and catechols (I) proceed via the initial electron transfer from 1 to **1DCA. 4-Hydroperoxy-2,5-cyclohexadien-1-ones and 4-hydroxy-2,5-cyclohexadien-1-ones are obtained from 2,4,6-trialkyl-substituted phenols, and an o-benzoquinone and furanone derivatives are afforded from 3,5-di-t-butylcatechol.

OXYGENATION OF 2,6-DI-t-BUTYLPHENOLS WITH SUPEROXO Co(lll) COMPLEXES

Superoxo Co(lll) complexes, *3 where X= Et3N(+) and (Ph3P)2N(+), mediate the dioxygen incorporation into 2,6-di-t-butylphenols (1) with the same regioselectivity as that in the base-catalyzed oxygenation of 1.The superoxo species acts as a base but is not incorporated into the substrate.