bis(trifluoromethyl)phosphinous bromide

Base Information

• Chemical Name: bis(trifluoromethyl)phosphinous bromide
• CAS No.: 758-45-2
• Molecular Formula: C₂BrF₆P
• Molecular Weight: 248.89
• Mol file: 758-45-2.mol

Synonyms:bis(trifluoromethyl)bromophosphane

Chemical Property of bis(trifluoromethyl)phosphinous bromide

Chemical Property:

• Vapor Pressure: 357mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(trifluoromethyl)phosphinous bromide

There total 4 articles about bis(trifluoromethyl)phosphinous bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

{bis(trifluoromethyl)thiophosphoryl}thio-bis(trifluoromethyl)phosphine (23526-69-4) → disulphur dibromide (13172-31-1) + bis(trifluoromethyl)bromophosphane (758-45-2) + Bis(trifluormethyl)-thiophosphinsaeurebromid (18799-77-4)

Guidance literature:

bromolysis first at 0°C (1 h) finally at 20°C (24 h);

DOI:10.1021/ja00739a004

Reference yield:

Bis(trifluormethyl)-tribromphosphoran (753-83-3) → Bromotrifluoromethane (75-63-8) + bis(trifluoromethyl)bromophosphane (758-45-2) + phosphorus tribromide (7789-60-8)

Guidance literature:

90°C;

DOI:10.1021/ja01499a009

Reference yield:

Bis(heptafluor-n-propyl)-trichlorphosphoran (1764-51-8) → Bromotrifluoromethane (75-63-8) + bis(trifluoromethyl)bromophosphane (758-45-2)

Guidance literature:

DOI:10.1021/ja01499a009

upstream raw materials:

{bis(trifluoromethyl)thiophosphoryl}thio-bis(trifluoromethyl)phosphine

bromine

Bis(trifluormethyl)-tribromphosphoran

Bis(heptafluor-n-propyl)-trichlorphosphoran

Downstream raw materials:

bromopentacarbonylmanganese(I)

bis(trifluoromethyl)phosphine

Bis--acetoxyphosphin