zinc(II)-5-(4-azidophenyl)-10,15,20-tris-(3,5-di-tert-butylphenyl)porphyrin

Base Information

• Chemical Name: zinc(II)-5-(4-azidophenyl)-10,15,20-tris-(3,5-di-tert-butylphenyl)porphyrin
• CAS No.: 1073615-95-8
• Molecular Formula: C₆₈H₇₅N₇Zn
• Molecular Weight: 1055.78

Synonyms:zinc(II)-5-(4-azidophenyl)-10,15,20-tris-(3,5-di-tert-butylphenyl)porphyrin

Chemical Property of zinc(II)-5-(4-azidophenyl)-10,15,20-tris-(3,5-di-tert-butylphenyl)porphyrin

Chemical Property:

Purity/Quality:

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Technology Process of zinc(II)-5-(4-azidophenyl)-10,15,20-tris-(3,5-di-tert-butylphenyl)porphyrin

There total 10 articles about zinc(II)-5-(4-azidophenyl)-10,15,20-tris-(3,5-di-tert-butylphenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

sodium azide + 5-(4-aminophenyl)-10,15,20-tris(3,5-di-tert-butylphenyl) porphyrin + zinc(II) acetate dihydrate (5970-45-6) → zinc(II)-5-(4-azidophenyl)-10,15,20-tris-(3,5-di-tert-butylphenyl)porphyrin (1073615-95-8)

Guidance literature:

With sodium nitrite; trifluoroacetic acid; In methanol; dichloromethane; to soln. aminophenylporphyrin in TFA at 0°C aq. soln. NaNO3 was added, stirred for 15 min at 0°C, aq. soln. NaN3 was added, stirred for 1 h, react. mixt. was extd. with CH2Cl2, ZnOAc in MeOH was added, refluxed for 1 h; react. mixt. was washed with water, dried over MgSO4 and filtered, flashchromy on silica (CH2Cl2-hexane 2:1);

DOI:10.1021/ja202485s

Reference yield:

3,5-Di-tert-butylbenzaldehyde (17610-00-3) → zinc(II)-5-(4-azidophenyl)-10,15,20-tris-(3,5-di-tert-butylphenyl)porphyrin (1073615-95-8)

Guidance literature:

Multi-step reaction with 5 steps

1.1: trifluoroacetic acid / dichloromethane / 1.5 h / 20 °C / Inert atmosphere

2.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 1 h / 20 °C

3.1: hydrogenchloride; water / ethanol / 17 h / Reflux

4.1: trifluoroacetic acid; sodium nitrite / water / 0.25 h / 0 °C

4.2: 1 h / 0 °C

5.1: zinc(II) acetate dihydrate / methanol / 1 h / Reflux

With hydrogenchloride; water; zinc(II) acetate dihydrate; trifluoroacetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium nitrite; In methanol; ethanol; dichloromethane; water;

DOI:10.1021/ja202485s

Reference yield:

C68H77N7 → zinc(II)-5-(4-azidophenyl)-10,15,20-tris-(3,5-di-tert-butylphenyl)porphyrin (1073615-95-8)

Guidance literature:

With zinc(II) acetate dihydrate; In methanol; for 1h; Reflux;

DOI:10.1021/ja202485s

upstream raw materials:

3,5-Di-tert-butylbenzaldehyde

zinc(II) acetate dihydrate

5-(4-azidophenyl)-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrin

zinc diacetate

Downstream raw materials:

Zn(N₄C₂₀H₈(C₆H₃(C(CH₃)3)2)3C₆H₄N₃C₂HC₆H₄CHO)

Zn(N₄C₂₀H₈(C₆H₃(C(CH₃)3)2)3C₆H₄N₃C₂HC₆H₄CHO)

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