(E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate

Base Information

Chemical Name:(E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate
CAS No.:303779-99-9
Molecular Formula:C₁₂H₁₇F₃O₃S
Molecular Weight:298.326
Hs Code.:

Synonyms:(E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate

Suppliers and Price of (E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate

There total 3 articles about (E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 472-66-2
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

: phenylbis[(trifluoromethyl)sulfonyl]amine

: 303779-99-9
(E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate

Guidance literature:: (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 ℃; for 2h;

phenylbis[(trifluoromethyl)sulfonyl]amine; In tetrahydrofuran; hexane; at -78 ℃; stereoselective reaction; Cooling;
DOI:10.1039/b813760a

Reference yield: 58.0%

: 37595-74-7
N,N-phenylbistrifluoromethane-sulfonimide

: 472-66-2
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

: 303779-99-9
(E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate

Guidance literature:: (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde; With potassium tert-butylate; In tetrahydrofuran; at 0 ℃; for 0.25h;

N,N-phenylbistrifluoromethane-sulfonimide; In tetrahydrofuran; at 20 ℃; for 0.5h;
DOI:10.1248/cpb.48.1391

Reference yield:

: 472-66-2
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

: phenylbis[(trifluoromethyl)sulfonyl]amine

: (Z)-2-(2,2,6-trimethylcyclohexen-1-yl)ethenyl trifluoromethanesulfonate

: 303779-99-9
(E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate

Guidance literature:: (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde; With potassium tert-butylate;

phenylbis[(trifluoromethyl)sulfonyl]amine; optical yield given as %de; stereoselective reaction;
DOI:10.1039/b813760a