S(-)-o'-(1,1'-binaphthyl-2,2'-diyl)bis(diphenylphosphane)platinum(II) triflate

Base Information

• Chemical Name: S(-)-o'-(1,1'-binaphthyl-2,2'-diyl)bis(diphenylphosphane)platinum(II) triflate
• CAS No.: 171415-15-9
• Molecular Formula: C₄₆H₃₂F₆O₆P₂PtS₂*H₂O
• Molecular Weight: 1133.92
• Mol file: 171415-15-9.mol

Synonyms:S(-)-o'-(1,1'-binaphthyl-2,2'-diyl)bis(diphenylphosphane)platinum(II) triflate

Chemical Property of S(-)-o'-(1,1'-binaphthyl-2,2'-diyl)bis(diphenylphosphane)platinum(II) triflate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of S(-)-o'-(1,1'-binaphthyl-2,2'-diyl)bis(diphenylphosphane)platinum(II) triflate

There total 4 articles about S(-)-o'-(1,1'-binaphthyl-2,2'-diyl)bis(diphenylphosphane)platinum(II) triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

[PdCl2{(S)-BINAP}] (126860-27-3,140224-25-5) + silver trifluoromethanesulfonate (2923-28-6) → (C10H6)2(P(C6H5)2)2Pt(OSO2CF3)2*H2O (171415-15-9)

Guidance literature:

In dichloromethane; (N2); stirring (room temp., 5 days), filtration, concn. of the filtrate; pptn. (diethyl ether); elem. anal.;

DOI:10.1021/ja961444r

Reference yield: 69.0%

PtCl2((R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl) (126860-27-3,140224-25-5) + water (7732-18-5) + silver trifluoromethanesulfonate (2923-28-6) → [Pt((R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(H2O)(triflate)](triflate) (171415-15-9)

Guidance literature:

In dichloromethane; N2-atmosphere; stirring Pt-complex with AgOTf for 4 d at room temp., filtration, concn., addn. of H2O; pptn. on addn. of Et2O, collection (filtration), washing (ether), drying(vac.); elem. anal.;

DOI:10.1021/om00011a052

Reference yield:

(R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthalene (76189-55-4,76189-56-5,98327-87-8) → [Pt((R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)(H2O)(triflate)](triflate) (171415-15-9)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane

2: dichloromethane

In dichloromethane;

DOI:10.1021/om00011a052

upstream raw materials:

PtCl₂((R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)

silver trifluoromethanesulfonate

[PdCl₂{(S)-BINAP}]

water