Technology Process of C37H56O7
There total 10 articles about C37H56O7 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
diisobutylaluminium hydride;
In
toluene;
at -20 ℃;
for 1h;
DOI:10.1021/ol201426c
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: Hoveyda-Grubbs catalyst second generation / toluene / 18 h / 25 °C / Reflux
2.1: triethylamine; (-)-diisopinocamphenylborane chloride / diethyl ether / 1 h / 0 °C
2.2: 18 h / -78 - -20 °C
3.1: tetramethylammonium triacetoxyborohydride / acetic acid; acetonitrile / 4 h / -20 - 25 °C
4.1: pyridinium p-toluenesulfonate / dichloromethane / 2 h / 0 - 25 °C
5.1: diisobutylaluminium hydride / toluene / 1 h / -20 °C
With
Hoveyda-Grubbs catalyst second generation; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; triethylamine; (-)-diisopinocamphenylborane chloride; tetramethylammonium triacetoxyborohydride;
In
diethyl ether; dichloromethane; acetic acid; toluene; acetonitrile;
2.2: Aldol condensation;
DOI:10.1021/ol201426c
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: lithium chloride; lithium diisopropyl amide / tetrahydrofuran / 1.33 h / -78 - 25 °C
1.2: 3 h / 0 - 25 °C
2.1: tetrahydrofuran; diethyl ether / -78 - 0 °C
3.1: triethylamine; (-)-diisopinocamphenylborane chloride / diethyl ether / 1 h / 0 °C
3.2: 18 h / -78 - -20 °C
4.1: tetramethylammonium triacetoxyborohydride / acetic acid; acetonitrile / 4 h / -20 - 25 °C
5.1: pyridinium p-toluenesulfonate / dichloromethane / 2 h / 0 - 25 °C
6.1: diisobutylaluminium hydride / toluene / 1 h / -20 °C
With
pyridinium p-toluenesulfonate; diisobutylaluminium hydride; triethylamine; (-)-diisopinocamphenylborane chloride; lithium chloride; tetramethylammonium triacetoxyborohydride; lithium diisopropyl amide;
In
tetrahydrofuran; diethyl ether; dichloromethane; acetic acid; toluene; acetonitrile;
3.2: Aldol condensation;
DOI:10.1021/ol201426c
