thallium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

Base Information

• Chemical Name: thallium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
• CAS No.: 188019-19-4
• Molecular Formula: C₃₂H₁₂BF₂₄*Tl
• Molecular Weight: 1067.6
• Mol file: 188019-19-4.mol

Synonyms:thallium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

Chemical Property of thallium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of thallium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

There total 2 articles about thallium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

H(O(C2H5)2)3(1+)*B(C6H3(CF3)2)4(1-)=[H(O(C2H5)2)3][B(C6H3(CF3)2)4] + thallium (I) ethoxide (20398-06-5) → thallium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate (188019-19-4)

Guidance literature:

In diethyl ether; N2-atmosphere; equimolar amts., stirring for 15 min at room temp.; solvent removal (vac.);

Reference yield: 75.0%

thallium(I) nitrate + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → thallium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate (188019-19-4)

Guidance literature:

In ethanol; water; at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1021/ic5025586

Reference yield: 96.0%

thallium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate (188019-19-4) + C36H33Br2N7Ni → C36H33BrN7Ni(1+)*C32H12BF24(1-)

Guidance literature:

In acetonitrile; for 0.166667h;

DOI:10.1039/d0cc07216h

upstream raw materials:

thallium (I) ethoxide

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

Downstream raw materials:

[Pd(η3-C4H7)(2-(4-bromo-1H-pyrazol-1-yl)pyrimidine)][tetrakis(3,5-trifluoromethylphenyl)borate]

[Pd(η3-C4H7)(2-(4-methyl-1H-pyrazol-1-yl)pyrimidine)][tetrakis(3,5-trifluoromethylphenyl)borate]

trans-[Ru(DMeOPrPE)2(η2-H2)H][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate]

[((η3-allyl)Pd(P-i-Pr3))2(μ-Cl)][B(3,5-C6H3(CF3)2)4]