cis-(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)platinum(II) chloride

Base Information

Chemical Name:cis-(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)platinum(II) chloride
CAS No.:205319-14-8
Molecular Formula:C₃₉H₃₂Cl₂OP₂Pt
Molecular Weight:844.616
Hs Code.:

Synonyms:cis-(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)platinum(II) chloride

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Chemical Property of cis-(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)platinum(II) chloride

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Technology Process of cis-(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)platinum(II) chloride

There total 7 articles about cis-(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)platinum(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 14873-63-3
cis-bis(benzonitrile)dichloroplatinum(II)

: 161265-03-8
4,5-bis(diphenylphosphino)-9,9-dimethylxanthene

: 205319-14-8
cis-(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)platinum(II) chloride

Guidance literature:: In benzene; under Ar; degassed soln. of Pt complex in benzene heated to 80°C for ca. 5 min; degassed soln. of ligand (1 equiv.) added; refluxed for 1h; stirred at room temp. for 16 h; ppt. washed with benzene and hexane; dried in vac.; elem. anal.;
DOI:10.1016/j.jorganchem.2003.10.045

Reference yield: 83.0%

: 161265-03-8
4,5-bis(diphenylphosphino)-9,9-dimethylxanthene

: 205319-14-8
cis-(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)platinum(II) chloride

Guidance literature:: With chloro-platinum(II) compound; In tetrahydrofuran; N2 atmosphere, stirring (room temp., overnight); removement of solvent (vacuum), washing (Et2O), drying (vacuum);
DOI:10.1002/(SICI)1099-0682(199802)1998:2<155::AID-EJIC155>3.0.CO;2-T

Reference yield:

: 161265-03-8
4,5-bis(diphenylphosphino)-9,9-dimethylxanthene

: 205319-14-8
cis-(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)platinum(II) chloride

: 1191427-26-5
[Pt(η3-allyl)(xantphos)]Cl

Guidance literature:: Multi-step reaction with 3 steps

1: chloroform

2: NaBH₄ / tetrahydrofuran; water

3: d₇-N,N-dimethylformamide

With NaBH₄; In tetrahydrofuran; chloroform; d₇-N,N-dimethylformamide; water;
DOI:10.1021/ja9046075