[((Z)-2-Hex-3-ene-1,5-diynyl)-phenylethynyl]-triisopropyl-silane

Base Information

• Chemical Name: [((Z)-2-Hex-3-ene-1,5-diynyl)-phenylethynyl]-triisopropyl-silane
• CAS No.: 482294-19-9
• Molecular Formula: C₂₃H₂₈Si
• Molecular Weight: 332.561
• Mol file: 482294-19-9.mol

Synonyms:[((Z)-2-Hex-3-ene-1,5-diynyl)-phenylethynyl]-triisopropyl-silane

Chemical Property of [((Z)-2-Hex-3-ene-1,5-diynyl)-phenylethynyl]-triisopropyl-silane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [((Z)-2-Hex-3-ene-1,5-diynyl)-phenylethynyl]-triisopropyl-silane

There total 3 articles about [((Z)-2-Hex-3-ene-1,5-diynyl)-phenylethynyl]-triisopropyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-ethynyl-1-[(triisopropylsilyl)ethynyl]benzene (335378-29-5) → [((Z)-2-Hex-3-ene-1,5-diynyl)-phenylethynyl]-triisopropyl-silane (482294-19-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 87 percent / PrNH₂; Pd(PPh₃)4; CuI / tetrahydrofuran

2: NaH / methanol; tetrahydrofuran / 0.5 h

With propylamine; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium hydride; In tetrahydrofuran; methanol;

DOI:10.1021/jo020463i

Reference yield:

triisopropyl((2-((trimethylsilyl)ethynyl) phenyl)ethynyl)silane (188003-93-2) → [((Z)-2-Hex-3-ene-1,5-diynyl)-phenylethynyl]-triisopropyl-silane (482294-19-9)

Guidance literature:

Multi-step reaction with 3 steps

1: K₂CO₃ / methanol; tetrahydrofuran

2: CuI; PrNH₂ / Pd(PPh₃)4 / tetrahydrofuran

3: K₂CO₃ / methanol; tetrahydrofuran

With propylamine; copper(l) iodide; potassium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; methanol;

DOI:10.1021/ol016764g

Reference yield:

1-[(Triisopropylsilanyl)-ethynyl]-2-((Z)-6-trimethylsilanyl-hex-3-ene-1,5-diynyl)-benzene (381173-13-3) → [((Z)-2-Hex-3-ene-1,5-diynyl)-phenylethynyl]-triisopropyl-silane (482294-19-9)

Guidance literature:

With potassium carbonate; In tetrahydrofuran; methanol;

DOI:10.1021/ol016764g

upstream raw materials:

1-[(Triisopropylsilanyl)-ethynyl]-2-((Z)-6-trimethylsilanyl-hex-3-ene-1,5-diynyl)-benzene

2-ethynyl-1-[(triisopropylsilyl)ethynyl]benzene

triisopropyl((2-((trimethylsilyl)ethynyl) phenyl)ethynyl)silane

Downstream raw materials:

1-[(Triisopropylsilanyl)-ethynyl]-2-((3Z,7Z)-10-trimethylsilanyl-deca-3,7-diene-1,5,9-triynyl)-benzene

1-((3Z,7Z)-Deca-3,7-diene-1,5,9-triynyl)-2-ethynyl-benzene