triisopropyl((2-((trimethylsilyl)ethynyl) phenyl)ethynyl)silane

Base Information

• Chemical Name: triisopropyl((2-((trimethylsilyl)ethynyl) phenyl)ethynyl)silane
• CAS No.: 188003-93-2
• Molecular Formula: C₂₂H₃₄Si₂
• Molecular Weight: 354.683
• Mol file: 188003-93-2.mol

Synonyms:triisopropyl((2-((trimethylsilyl)ethynyl) phenyl)ethynyl)silane

Chemical Property of triisopropyl((2-((trimethylsilyl)ethynyl) phenyl)ethynyl)silane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of triisopropyl((2-((trimethylsilyl)ethynyl) phenyl)ethynyl)silane

There total 2 articles about triisopropyl((2-((trimethylsilyl)ethynyl) phenyl)ethynyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

2-bromo-1-(trimethylsilylethynyl)benzene (38274-16-7) + tris-iso-propylsilyl acetylene (89343-06-6) → triisopropyl((2-((trimethylsilyl)ethynyl) phenyl)ethynyl)silane (188003-93-2)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; at 120 ℃;

DOI:10.1016/S0040-4020(01)00229-0

Reference yield: 73.0%

1-Bromo-2-iodobenzene (583-55-1) + tris-iso-propylsilyl acetylene (89343-06-6) + trimethylsilylacetylene (1066-54-2) → triisopropyl((2-((trimethylsilyl)ethynyl) phenyl)ethynyl)silane (188003-93-2)

Guidance literature:

1-Bromo-2-iodobenzene; trimethylsilylacetylene; With copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride;

tris-iso-propylsilyl acetylene; With copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride;

DOI:10.1021/ja964048h

Reference yield: 100.0%

triisopropyl((2-((trimethylsilyl)ethynyl) phenyl)ethynyl)silane (188003-93-2) → 2-ethynyl-1-[(triisopropylsilyl)ethynyl]benzene (335378-29-5)

Guidance literature:

With potassium carbonate; In methanol; diethyl ether; for 2h;

DOI:10.1016/S0040-4020(01)00229-0

upstream raw materials:

1-Bromo-2-iodobenzene

tris-iso-propylsilyl acetylene

trimethylsilylacetylene

2-bromo-1-(trimethylsilylethynyl)benzene

Downstream raw materials:

2-ethynyl-1-[(triisopropylsilyl)ethynyl]benzene

1-((3Z,7Z)-Deca-3,7-diene-1,5,9-triynyl)-2-ethynyl-benzene

[((Z)-2-Hex-3-ene-1,5-diynyl)-phenylethynyl]-triisopropyl-silane

1-[(Triisopropylsilanyl)-ethynyl]-2-((Z)-6-trimethylsilanyl-hex-3-ene-1,5-diynyl)-benzene