{(R)-2-[(2R,3S)-3-((R)-1-Allyloxy-2-benzyloxy-ethyl)-oxiranyl]-propoxy}-tert-butyl-dimethyl-silane

Base Information

Chemical Name:{(R)-2-[(2R,3S)-3-((R)-1-Allyloxy-2-benzyloxy-ethyl)-oxiranyl]-propoxy}-tert-butyl-dimethyl-silane
CAS No.:128625-97-8
Molecular Formula:C₂₃H₃₈O₄Si
Molecular Weight:406.638
Hs Code.:

Synonyms:{(R)-2-[(2R,3S)-3-((R)-1-Allyloxy-2-benzyloxy-ethyl)-oxiranyl]-propoxy}-tert-butyl-dimethyl-silane

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Chemical Property of {(R)-2-[(2R,3S)-3-((R)-1-Allyloxy-2-benzyloxy-ethyl)-oxiranyl]-propoxy}-tert-butyl-dimethyl-silane

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Technology Process of {(R)-2-[(2R,3S)-3-((R)-1-Allyloxy-2-benzyloxy-ethyl)-oxiranyl]-propoxy}-tert-butyl-dimethyl-silane

There total 7 articles about {(R)-2-[(2R,3S)-3-((R)-1-Allyloxy-2-benzyloxy-ethyl)-oxiranyl]-propoxy}-tert-butyl-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 556-56-9
allyl iodid

: 128625-96-7,128705-93-1
(R)-2-Benzyloxy-1-{(2R,3R)-3-[(R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-oxiranyl}-ethanol

: 128625-97-8
{(R)-2-[(2R,3S)-3-((R)-1-Allyloxy-2-benzyloxy-ethyl)-oxiranyl]-propoxy}-tert-butyl-dimethyl-silane

Guidance literature:: With silver(l) oxide;
DOI:10.1016/S0040-4039(00)94430-7

Reference yield:

: 128625-93-4,150950-19-9
(E)-(2R,3S)-6-Benzyloxy-3-(dimethyl-phenyl-silanyl)-2-methyl-hex-4-enoic acid methyl ester

: 128625-97-8
{(R)-2-[(2R,3S)-3-((R)-1-Allyloxy-2-benzyloxy-ethyl)-oxiranyl]-propoxy}-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 5 steps

1: 1) DIBAL 2) iPr₂NEt / 1.) CH₂Cl₂ 2.) THF

2: m-CPBA / CH₂Cl₂ / -20 °C

3: AcOH, H₂O / tetrahydrofuran / Ambient temperature

4: t-BuOOH/VO(acac)2

5: 90 percent / Ag₂O

With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; water; diisobutylaluminium hydride; acetic acid; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; silver(l) oxide; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(00)94430-7

Reference yield:

: 128625-94-5
C₂₈H₄₄O₂Si₂

: 128625-97-8
{(R)-2-[(2R,3S)-3-((R)-1-Allyloxy-2-benzyloxy-ethyl)-oxiranyl]-propoxy}-tert-butyl-dimethyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1: m-CPBA / CH₂Cl₂ / -20 °C

2: AcOH, H₂O / tetrahydrofuran / Ambient temperature

3: t-BuOOH/VO(acac)2

4: 90 percent / Ag₂O

With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; water; acetic acid; 3-chloro-benzenecarboperoxoic acid; silver(l) oxide; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(00)94430-7