Technology Process of C49H72O7SSi
There total 8 articles about C49H72O7SSi which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C42H66O7SSi;
With
sodium hydride;
In
tetrahydrofuran; mineral oil;
at 20 ℃;
for 2h;
benzyl bromide;
With
tetra-(n-butyl)ammonium iodide;
In
tetrahydrofuran; mineral oil;
for 15h;
DOI:10.1021/ol102925d
- Guidance literature:
-
Multi-step reaction with 7 steps
1.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 0 °C
1.2: 1 h / 50 °C
2.1: dimethylsulfide borane complex / tetrahydrofuran / 0 - 20 °C
2.2: 0 - 20 °C
3.1: diisobutylaluminium hydride / hexane; dichloromethane / 0 - 20 °C
3.2: 2.5 h
4.1: 1H-imidazole / N,N-dimethyl-formamide / 20 °C
5.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 19 h / 20 °C / Molecular sieve
6.1: zinc trifluoromethanesulfonate / tetrahydrofuran / 20 °C
7.1: sodium hydride / tetrahydrofuran; mineral oil / 2 h / 20 °C
7.2: 15 h
With
1H-imidazole; tetrapropylammonium perruthennate; dimethylsulfide borane complex; zinc trifluoromethanesulfonate; sodium hydride; diisobutylaluminium hydride; 4-methylmorpholine N-oxide; 9-bora-bicyclo[3.3.1]nonane;
In
tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; mineral oil;
1.2: Suzuki-Miyaura coupling;
DOI:10.1021/ol102925d
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: dimethylsulfide borane complex / tetrahydrofuran / 0 - 20 °C
1.2: 0 - 20 °C
2.1: diisobutylaluminium hydride / hexane; dichloromethane / 0 - 20 °C
2.2: 2.5 h
3.1: 1H-imidazole / N,N-dimethyl-formamide / 20 °C
4.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 19 h / 20 °C / Molecular sieve
5.1: zinc trifluoromethanesulfonate / tetrahydrofuran / 20 °C
6.1: sodium hydride / tetrahydrofuran; mineral oil / 2 h / 20 °C
6.2: 15 h
With
1H-imidazole; tetrapropylammonium perruthennate; dimethylsulfide borane complex; zinc trifluoromethanesulfonate; sodium hydride; diisobutylaluminium hydride; 4-methylmorpholine N-oxide;
In
tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1021/ol102925d
