1-O-{11-[4-(4-methylbenzoyl)-phenyl]-undecyl}-2-O-tetrahydropyranyl-3-O-acetyl-sn-glycerol

Base Information

Chemical Name:1-O-{11-[4-(4-methylbenzoyl)-phenyl]-undecyl}-2-O-tetrahydropyranyl-3-O-acetyl-sn-glycerol
CAS No.:685888-19-1
Molecular Formula:C₃₅H₅₀O₆
Molecular Weight:566.778
Hs Code.:

Synonyms:1-O-{11-[4-(4-methylbenzoyl)-phenyl]-undecyl}-2-O-tetrahydropyranyl-3-O-acetyl-sn-glycerol

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Chemical Property of 1-O-{11-[4-(4-methylbenzoyl)-phenyl]-undecyl}-2-O-tetrahydropyranyl-3-O-acetyl-sn-glycerol

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Technology Process of 1-O-{11-[4-(4-methylbenzoyl)-phenyl]-undecyl}-2-O-tetrahydropyranyl-3-O-acetyl-sn-glycerol

There total 9 articles about 1-O-{11-[4-(4-methylbenzoyl)-phenyl]-undecyl}-2-O-tetrahydropyranyl-3-O-acetyl-sn-glycerol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 3396-11-0
cesium acetate

: 685887-98-3
1-O-{11-[4-(4-methylbenzoyl)-phenyl]-undecyl}-2-O-tetrahydropyranyl-3-O-tosyl-sn-glycerol

: 685888-19-1
1-O-{11-[4-(4-methylbenzoyl)-phenyl]-undecyl}-2-O-tetrahydropyranyl-3-O-acetyl-sn-glycerol

Guidance literature:: In dimethyl sulfoxide; N,N-dimethyl-formamide; at 20 ℃; for 48h;

Reference yield:

: 108-86-1,52753-63-6
bromobenzene

: 685888-19-1
1-O-{11-[4-(4-methylbenzoyl)-phenyl]-undecyl}-2-O-tetrahydropyranyl-3-O-acetyl-sn-glycerol

Guidance literature:: Multi-step reaction with 6 steps

1.1: AlCl₃ / CH₂Cl₂ / 2 h / 5 - 20 °C

1.2: 61 percent / CH₂Cl₂ / 20 h / 20 °C

2.1: 9-BBN / tetrahydrofuran / 3 h / 20 °C

2.2: 97 percent / Cs₂CO₃; Ph₃As; Pd(dppf)Cl₂*CH₂Cl₂ / dimethylformamide; tetrahydrofuran; H₂O

3.1: 81 percent / KOH / ethanol; H₂O / 0.67 h / 20 °C

4.1: 81 percent / BF₃*OEt₂ / CHCl₃ / 20 °C

5.1: 100 percent / PPTS / CH₂Cl₂ / 20 °C

6.1: 76 percent / dimethylsulfoxide; dimethylformamide / 48 h / 20 °C

With potassium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; aluminium trichloride; boron trifluoride diethyl etherate; pyridinium p-toluenesulfonate; In tetrahydrofuran; ethanol; dichloromethane; chloroform; water; dimethyl sulfoxide; N,N-dimethyl-formamide; 1.1: Friedel-Crafts reaction;

Reference yield:

: 112-43-6
10-Undecen-1-ol

: 685888-19-1
1-O-{11-[4-(4-methylbenzoyl)-phenyl]-undecyl}-2-O-tetrahydropyranyl-3-O-acetyl-sn-glycerol

Guidance literature:: Multi-step reaction with 6 steps

1.1: 99 percent / Et₃N; N,N-dimethylaminopyridine / 24 h / 20 °C

2.1: 9-BBN / tetrahydrofuran / 3 h / 20 °C

2.2: 97 percent / Cs₂CO₃; Ph₃As; Pd(dppf)Cl₂*CH₂Cl₂ / dimethylformamide; tetrahydrofuran; H₂O

3.1: 81 percent / KOH / ethanol; H₂O / 0.67 h / 20 °C

4.1: 81 percent / BF₃*OEt₂ / CHCl₃ / 20 °C

5.1: 100 percent / PPTS / CH₂Cl₂ / 20 °C

6.1: 76 percent / dimethylsulfoxide; dimethylformamide / 48 h / 20 °C

With dmap; potassium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; boron trifluoride diethyl etherate; pyridinium p-toluenesulfonate; triethylamine; In tetrahydrofuran; ethanol; dichloromethane; chloroform; water; dimethyl sulfoxide; N,N-dimethyl-formamide;