10-Undecen-1-OL

Base Information

• Chemical Name: 10-Undecen-1-OL
• CAS No.: 112-43-6
• Deprecated CAS: 118020-80-7,1082770-76-0,1082770-76-0
• Molecular Formula: C11H22 O
• Molecular Weight: 170.295
• Hs Code.: 2905.19
• European Community (EC) Number: 203-971-0
• NSC Number: 66157
• UNII: G63HL09NXK
• DSSTox Substance ID: DTXSID4059419
• Nikkaji Number: J22.115E
• Wikidata: Q18611668
• Metabolomics Workbench ID: 44658
• Mol file: 112-43-6.mol

Synonyms:10-UNDECEN-1-OL;112-43-6;undec-10-en-1-ol;Undecylenic alcohol;Undecylenyl alcohol;10-Undecenol;1-Undecen-11-ol;11-Hydroxy-1-undecene;10-Undecylen-1-ol;omega-Undecenyl alcohol;Undecen-1-ol;.omega.-Undecenyl alcohol;Undec-10-enol;10-Undecene-1-ol;C-11 Alcohol;EINECS 203-971-0;NSC 66157;UNII-G63HL09NXK;.omega.-Undecylenyl alcohol;BRN 1753225;G63HL09NXK;AI3-06259;MFCD00004750;NSC-66157;4-01-00-02194 (Beilstein Handbook Reference);10-undecenyl alcohol;omega-undecylenyl alcoho;omega-Undecylenyl alcohol;.OMEGA.-UNDECENOL;SCHEMBL41157;UNDEC-1O-EN-1-OL;CH2=CH(CH2)9OH;UNDECEN-1-OL [FHFI];10-Undecen-1-ol, 98%;Undec- 10- en- 1- ol;WLN: Q10U1;DTXSID4059419;AMY5942;CHEBI:131344;laquo Omegaraquo -undecenyl alcohol;NSC66157;STR02738;laquo Omegaraquo -undecylenyl alcohol;LMFA05000587;s6225;undec - 10 - en - 1 - ol;10-Undecen-1-ol, analytical standard;AKOS015903579;CS-W004298;HY-W004298;LS-3147;SY011350;FT-0607199;U0047;10-Undecen-1-ol, >=98%, stabilized, FG;EN300-108628;Q18611668;Z1255430980

Chemical Property of 10-Undecen-1-OL

Chemical Property:

• Appearance/Colour: clear liquid
• Vapor Pressure: 0.00354mmHg at 25°C
• Melting Point: -3 °C
• Refractive Index: 1.448
• Boiling Point: 132 - 133 at 15 hPa
• PKA: 15.20±0.10(Predicted)
• Flash Point: 93.3°C
• PSA: 20.23000
• Density: 0.84g/cm³
• LogP: 3.28550
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility.: Chloroform (Sparingly), Methanol (Slightly)
• Water Solubility.: Miscible with alcohol and ether. Immiscible with water.
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 9
• Exact Mass: 170.167065321
• Heavy Atom Count: 12
• Complexity: 89

Purity/Quality:

98%, ^*data from raw suppliers

10-Undecen-1-ol ^*data from reagent suppliers

Safty Information:

• Pictogram(s): UN NO.
• Hazard Codes: Xi
• Statements: 36/38
• Safety Statements: 37/39-26-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Alcohols and Polyols, Other
• Canonical SMILES: C=CCCCCCCCCCO
• Uses: 10-Undecen-1-ol is used as a flavoring agent. It reacts with tosylated beta-cyclodextrin to prepare beta-cyclodextrin undecenylether. It is used in the synthesis of 10-Undecenylacrylat by reacting with acryloyl and triethylamine. It reacts with carbon monoxide in the presence of dicobalt octacarbonyl and pyridine as a base at pressures greater than 150 bar and temperatures in the range of 100 to 2000C to linear and branched polyesters having relatively high molecular weights (Mn> 10,000 g / mol) in good yields.

Technology Process of 10-Undecen-1-OL

There total 69 articles about 10-Undecen-1-OL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

undec-10-yn-1-ol (2774-84-7) → 10-Undecen-1-ol (112-43-6)

Guidance literature:

With quinoline; hydrogen; Lindlar's catalyst; In ethanol; under 2585.81 Torr;

Reference yield: 99.0%

10-Undecenal (112-45-8) → 10-Undecen-1-ol (112-43-6)

Guidance literature:

10-Undecenal; With [CpFe(IMes)(CO)2]I; phenylsilane; In tetrahydrofuran; at 70 ℃; for 1h; Inert atmosphere; Irradiation;

With methanol; sodium hydroxide; In tetrahydrofuran; water; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/adsc.201000781

Reference yield: 99.0%

Methyl 10-undecenoate (111-81-9) → 10-Undecen-1-ol (112-43-6)

Guidance literature:

With diisobutylaluminium hydride; In tetrahydrofuran; hexane; at -78 ℃; for 5h;

DOI:10.1021/acs.orglett.9b03484

upstream raw materials:

(9Z,12R)-octadec-9-ene-1,12-diol

10-undecenoic acid

ethyl 10-undecenenoate

11-hydroxyundecan-2-one

Downstream raw materials:

undecyl alcohol

1,10-dibromoundecane

1-undecen-11-ylbromide

undecylaldehyde

Refernces

• 1、 Schulte,Mleinek. "-". . p. 483,485. Retrieved 1957.
• 2、 Epstein, Oleg L.,Kulinkovich, Oleg G.. "Titanium-mediated formation of 1,2-disubstituted cyclopropanols from esters and alkenes. A new approach to the synthesis of 3,11- dimethylnonacosan-2-one, a sex pheromone of the german cockroach". . p. 1823 - 1826. Retrieved 1998.
• 3、 Crouch, R. David,Mehlmann, John F.,Herb, Brian R.,Mitten, Jeffrey V.,Dai, H. George. "Selective conversion of enol ethers into alcohols in the presence of alkenes using Hg(OAc)2-NaBH4". . p. 559 - 561. Retrieved 1999.
• 4、 ?ztürk, Bengi ?zgün,?ztürk, Sinem. "Transfer-hydrogenation reactions of ketones/aldehydes in water using first generation ruthenium indenylidene olefin metathesis catalyst: One step towards sequential cross-metathesis/transfer hydrogenation reactions". . . Retrieved 2020.
• 5、 Babler, James H.,Invergo, Benedict J.. "REDUCTION OF ACID CHLORIDES WITH SODIUM BOROHYDRIDE IN N,N-DIMETHYLFORMAMIDE: NATURE OF THE REACTION INTERMEDIATE AND A METHOD FOR ITS CONVERSION TO THE CORRESPONDING ALDEHYDE WITH MINIMAL ALCOHOL FORMATION". . p. 11 - 14. Retrieved 1981.
• 6、 Oki,Iwamura. "-". . p. 567. Retrieved 1959.
• 7、 Jubeli, Emile,Maginty, Amanda B.,Khalique, Nada Abdul,Raju, Liji,Nicholson, David G.,Larsen, Helge,Pungente, Michael D.,Goldring, William P.D.. "Cationic lipids bearing succinic-based, acyclic and macrocyclic hydrophobic domains: Synthetic studies and in vitro gene transfer". . p. 225 - 232. Retrieved 2017.
• 8、 Sharma,Sankaranarayanan,Chattopadhyay. "Expedient synthesis of (R)-patulolide A". . p. 1814 - 1816. Retrieved 1996.
• 9、 Chakraborty, Soumi,Das, Arpan,Mandal, Swadhin K.. "Redox-active ligand based Mn(i)-catalyst for hydrosilylative ester reduction". supporting information. p. 12671 - 12674. Retrieved 2021/12/04.
• 10、 Bagh, Bidraha,Behera, Rakesh R.,Ghosh, Rahul,Khamari, Subrat,Panda, Surajit. "Hydrosilylation of Esters Catalyzed by Bisphosphine Manganese(I) Complex: Selective Transformation of Esters to Alcohols". supporting information. p. 3642 - 3648. Retrieved 2020/04/20.