(2,3,5,6-H)-BICYCLO[2.2.1]HEPTA-2,5-DIENE][(1S,1''S)-[1,2-ETHANEDIYLBIS[(2-METHOXYPHENYL)PHENYLPHOSPHINE]RHODIUM(I)- TETRAFLUOROBORATE

Base Information

Chemical Name:(2,3,5,6-H)-BICYCLO[2.2.1]HEPTA-2,5-DIENE][(1S,1''S)-[1,2-ETHANEDIYLBIS[(2-METHOXYPHENYL)PHENYLPHOSPHINE]RHODIUM(I)- TETRAFLUOROBORATE
CAS No.:75085-38-0
Molecular Formula:BF₄*C₃₅H₃₆O₂P₂Rh
Molecular Weight:740.327
Hs Code.:

Synonyms:(2,3,5,6-H)-BICYCLO[2.2.1]HEPTA-2,5-DIENE][(1S,1’’S)-[1,2-ETHANEDIYLBIS[(2-METHOXYPHENYL)PHENYLPHOSPHINE]RHODIUM(I)- TETRAFLUOROBORATE

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2,3,5,6-H)-BICYCLO[2.2.1]HEPTA-2,5-DIENE][(1S,1''S)-[1,2-ETHANEDIYLBIS[(2-METHOXYPHENYL)PHENYLPHOSPHINE]RHODIUM(I)- TETRAFLUOROBORATE

Chemical Property:

PSA：45.64000
LogP:7.29050

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (2,3,5,6-H)-BICYCLO[2.2.1]HEPTA-2,5-DIENE][(1S,1''S)-[1,2-ETHANEDIYLBIS[(2-METHOXYPHENYL)PHENYLPHOSPHINE]RHODIUM(I)- TETRAFLUOROBORATE

There total 1 articles about (2,3,5,6-H)-BICYCLO[2.2.1]HEPTA-2,5-DIENE][(1S,1''S)-[1,2-ETHANEDIYLBIS[(2-METHOXYPHENYL)PHENYLPHOSPHINE]RHODIUM(I)- TETRAFLUOROBORATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 863684-39-3,863615-57-0
[Rh((S,S)-DIPAMP)((Z)-2-benzoylamino-3-(3,4-dimethoxyphenyl)-methyl acrylate)]BF₄

: 121-46-0
bicyclo[2.2.1]hepta-2,5-diene

: 75085-38-0,1172584-50-7
{((R,R)-1,2-bis(phenyl-o-anisoylphosphino)ethane)(norbornadiene)}rhodium tetrafluoroborate

Guidance literature:: In d⁽⁴⁾-methanol; byproducts: (Z)-(MeO)2C6H3CHC(CO2Me)NHC(O)C6H5; Rh complex dissolved in CD3OD; ligand (10-fold excess) added at room temp.; monitored by (1)H and (31)P NMR spectra;
DOI:10.1021/om0490536

Reference yield:

: 75085-38-0,1172584-50-7
{((R,R)-1,2-bis(phenyl-o-anisoylphosphino)ethane)(norbornadiene)}rhodium tetrafluoroborate

: 106502-35-6
{R,R-1,2-bis((phenyl-o-anisoyl)phosphino)ethane}rhodium(I) tetrafluoroborate

Guidance literature:: With hydrogen; In methanol; stirred under H2 at room temp. until gas uptake ceased (ca 15 min); soln. cooled to -80°C, evacuated, diluted with diethyl ether, after warming to room temp. pptn., filtered in inert atmosphere, precipitate washed with diethyl ether, dried in vac.;
DOI:10.1021/ja00240a025

Reference yield:

: 75085-38-0,1172584-50-7
{((R,R)-1,2-bis(phenyl-o-anisoylphosphino)ethane)(norbornadiene)}rhodium tetrafluoroborate

: 79357-44-1
(Z)-N-Acetyl-α,β-didehydronorleucin-methylester

: {((R,R)-1,2-bis(phenyl-o-anisoylphosphino)ethane)(methyl(Z)-β-propyl-α-acetamidoacrylate)}rhodium tetrafluoroborate

Guidance literature:: With hydrogen; In methanol; stirring of Rh(norbornadiene)-complex in MeOH (H2 atmosphere, until color change to yellow), sepn. of H2 (N2 atmosphere), addn. of excess of ligand; recrystn. (MeOH);