CHLOROTHEXYLBORANE-METHYL SULFIDE COMPLEX)

Base Information

• Chemical Name: CHLOROTHEXYLBORANE-METHYL SULFIDE COMPLEX)
• CAS No.: 75067-06-0
• Molecular Formula: C8H20 B Cl S
• Molecular Weight: 194.577
• Mol file: 75067-06-0.mol

Synonyms:Borane,chloro(1,1,2-trimethylpropyl)-, compd. with thiobis[methane] (1:1); Butane, 2,3-dimethyl-,boron complex; Methane, thiobis-, boron complex; Methane, thiobis-, compd. withchloro(1,1,2-trimethylpropyl)borane (1:1); Chloro(dimethylsulfide)(hydro)(1,1,2-trimethylpropyl)boron; Thexylchloroborane-dimethylsulfide

Chemical Property of CHLOROTHEXYLBORANE-METHYL SULFIDE COMPLEX)

Chemical Property:

• PSA: 25.30000
• LogP: 3.41040

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of CHLOROTHEXYLBORANE-METHYL SULFIDE COMPLEX)

There total 2 articles about CHLOROTHEXYLBORANE-METHYL SULFIDE COMPLEX) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3-Dimethyl-2-butene (563-79-1) + monochloroborane dimethyl sulfide complex (63348-81-2) → thexylchloroborane*methyl sulfide (75067-06-0)

Guidance literature:

In dichloromethane; mixed at 0°C, stirring at 25°C; Kinetics;

Reference yield:

2,3-Dimethyl-2-butene (563-79-1) + dimethylsulfide (75-18-3) + BH2Cl*Et2O (36594-41-9) → thexylchloroborane*methyl sulfide (75067-06-0)

Guidance literature:

In diethyl ether; 0 °C, 30 - 60 min, methyl sulfide addition, 30 min;

Reference yield: 100.0%

oct-1-ene (111-66-0,25068-25-1) + thexylchloroborane * dimethylsulfide (75067-06-0) → octanol (111-87-5) + rac-octan-2-ol (4128-31-8,113301-48-7,4128-32-9) + 2,3-dimethylbutan-2-ol (594-60-5)

Guidance literature:

With methanol; dihydrogen peroxide; Product distribution; different solvents; other olefins;

DOI:10.1021/jo00344a022

upstream raw materials:

2,3-Dimethyl-2-butene

dimethylsulfide

BH₂Cl*Et₂O

monochloroborane dimethyl sulfide complex

Downstream raw materials:

octanol

rac-octan-2-ol

2,3-dimethylbutan-2-ol

(CH₃)2CHC(CH₃)2BCl₂(S(CH₃)2)