BORON MONOCHLORIDE-METHYL SULFIDE COMPLEX

Base Information

• Chemical Name: BORON MONOCHLORIDE-METHYL SULFIDE COMPLEX
• CAS No.: 63348-81-2
• Molecular Formula: C2H8 B Cl S
• Molecular Weight: 110.416
• Mol file: 63348-81-2.mol

Synonyms:Borane,chloro-, compd. with thiobis[methane] (1:1); Boron,chlorodihydro[thiobis[methane]]-, (T-4)- (9CI); Methane, thiobis-, boroncomplex; Methane, thiobis-, compd. with chloroborane (1:1); Chloro(dimethylsulfide)borane; Chloro(dimethyl sulfide)dihydroboron; Chloroborane-methylsulfide 1:1 complex; Monochloroborane-dimethyl sulfide (1:1)

Chemical Property of BORON MONOCHLORIDE-METHYL SULFIDE COMPLEX

Chemical Property:

• Flash Point: 76 °F
• PSA: 19.21000
• Density: 1.059 g/mL at 25 °C(lit.)
• LogP: 0.75250

Purity/Quality:

98%,99%, ^*data from raw suppliers

ChloroboraneMethylSulfideComplex(TechnicalGrade) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 10-14-34
• Safety Statements: 16-26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Reactant for:Substitution reactionsBoronation reactionsPreparation of diborylaminesPreparation of unsymmetrical borafluorenes via low-temperature carbon-hydrogen activation reactionsAsymmetrical aldol reactions with a-chiral aldehydesAddition reaction with α-pinene

Technology Process of BORON MONOCHLORIDE-METHYL SULFIDE COMPLEX

There total 2 articles about BORON MONOCHLORIDE-METHYL SULFIDE COMPLEX which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrachloromethane (56-23-5) + dimethylsulfide borane complex (13292-87-0) → monochloroborane dimethyl sulfide complex (63348-81-2)

Guidance literature:

byproducts: chloroform; reflux under Ar or N2 for 20 h;

DOI:10.1039/c39800001169

Reference yield:

→ monochloroborane dimethyl sulfide complex (63348-81-2)

Guidance literature:

Cl3B*S(CH3)2, H3B*S(CH3)2;

DOI:10.1021/jo00434a050

Reference yield: 93.0%

monochloroborane dimethyl sulfide complex (63348-81-2) + 1,8?bis(diphenylphosphino)naphthalene (153725-04-3) → [1,8-bis(diphenylphosphino)naphthalene]dihydroboron chloride (1186424-33-8)

Guidance literature:

In tetrahydrofuran; diethyl ether; under Ar; soln. of H2ClBSMe2 in Et2O added dropwise at room temp. to soln. of C10H6(PPh2)2 (molar ratio 1.2:1) in THF; stirred for 5 h; solvent removed under reduced pressure; washed with Et2O;

DOI:10.1021/om900017n

upstream raw materials:

tetrachloromethane

dimethylsulfide borane complex

Downstream raw materials:

dicyclohexylboron chloride

C₂H₅(H)BCl

diethylchloroborane

boron trichloride - methyl sulfide complex