2ξ-(2,6-dimethoxyphenylhydroxymethyl)-2ξ-hydroxy-3ξ-hydroxymethyl-7-oxabicyclo<2.2.1>heptane

Base Information

Chemical Name:2ξ-(2,6-dimethoxyphenylhydroxymethyl)-2ξ-hydroxy-3ξ-hydroxymethyl-7-oxabicyclo<2.2.1>heptane
CAS No.:76505-14-1
Molecular Formula:C₁₆H₂₂O₆
Molecular Weight:310.347
Hs Code.:

Synonyms:2ξ-(2,6-dimethoxyphenylhydroxymethyl)-2ξ-hydroxy-3ξ-hydroxymethyl-7-oxabicyclo<2.2.1>heptane

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Chemical Property of 2ξ-(2,6-dimethoxyphenylhydroxymethyl)-2ξ-hydroxy-3ξ-hydroxymethyl-7-oxabicyclo<2.2.1>heptane

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Technology Process of 2ξ-(2,6-dimethoxyphenylhydroxymethyl)-2ξ-hydroxy-3ξ-hydroxymethyl-7-oxabicyclo<2.2.1>heptane

There total 11 articles about 2ξ-(2,6-dimethoxyphenylhydroxymethyl)-2ξ-hydroxy-3ξ-hydroxymethyl-7-oxabicyclo<2.2.1>heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2785-97-9
(2,6-dimethoxyphenyl)lithium

: 76505-14-1
2ξ-(2,6-dimethoxyphenylhydroxymethyl)-2ξ-hydroxy-3ξ-hydroxymethyl-7-oxabicyclo<2.2.1>heptane

Guidance literature:: Multi-step reaction with 7 steps

1: 1.6 g

3: 0.2 g / toluene-p-sulphonic acid / benzene / 72 h / Heating

4: 70 percent / bromine / acetic acid / 0.5 h

5: lithium carbonate / dimethylformamide

6: 2 g / 30percent hydrogen peroxide, potassium carbonate / acetone; H₂O / 0 °C

7: 0.4 g / lithium aluminum hydride / diethyl ether / 5 h / Ambient temperature

With lithium aluminium tetrahydride; dihydrogen peroxide; bromine; lithium carbonate; potassium carbonate; toluene-4-sulfonic acid; In diethyl ether; water; acetic acid; N,N-dimethyl-formamide; acetone; benzene;

Reference yield:

: 76504-82-0,76504-83-1
2β-(2,6-dimethoxybenzoyl)-7-oxabicyclo<2.2.1>heptane-3β-carboxylic acid

: 76505-14-1
2ξ-(2,6-dimethoxyphenylhydroxymethyl)-2ξ-hydroxy-3ξ-hydroxymethyl-7-oxabicyclo<2.2.1>heptane

Guidance literature:: Multi-step reaction with 6 steps

1: 1.2 g

2: 0.96 g / sodium acetate, acetic acid / 6 h / Heating

3: 70 percent / bromine / acetic acid / 0.5 h

4: lithium carbonate / dimethylformamide

5: 2 g / 30percent hydrogen peroxide, potassium carbonate / acetone; H₂O / 0 °C

6: 0.4 g / lithium aluminum hydride / diethyl ether / 5 h / Ambient temperature

With lithium aluminium tetrahydride; dihydrogen peroxide; bromine; sodium acetate; lithium carbonate; potassium carbonate; acetic acid; In diethyl ether; water; acetic acid; N,N-dimethyl-formamide; acetone;

Reference yield:

: 76504-84-2,76582-15-5,76612-56-1
2α-(2,6-dimethoxybenzoyl)-3α-methoxycarbonyl-7-oxabicyclo<2.2.1>heptane

: 76505-14-1
2ξ-(2,6-dimethoxyphenylhydroxymethyl)-2ξ-hydroxy-3ξ-hydroxymethyl-7-oxabicyclo<2.2.1>heptane

Guidance literature:: Multi-step reaction with 5 steps

1: 0.2 g / toluene-p-sulphonic acid / benzene / 72 h / Heating

2: 70 percent / bromine / acetic acid / 0.5 h

3: lithium carbonate / dimethylformamide

4: 2 g / 30percent hydrogen peroxide, potassium carbonate / acetone; H₂O / 0 °C

5: 0.4 g / lithium aluminum hydride / diethyl ether / 5 h / Ambient temperature

With lithium aluminium tetrahydride; dihydrogen peroxide; bromine; lithium carbonate; potassium carbonate; toluene-4-sulfonic acid; In diethyl ether; water; acetic acid; N,N-dimethyl-formamide; acetone; benzene;