4-cyclohexyl-4-[dimethyl(phenyl)silyl]-4-[dimethyl(phenyl)silyloxy]but-1-ene

Base Information

Chemical Name:4-cyclohexyl-4-[dimethyl(phenyl)silyl]-4-[dimethyl(phenyl)silyloxy]but-1-ene
CAS No.:503606-94-8
Molecular Formula:C₂₆H₃₈OSi₂
Molecular Weight:422.758
Hs Code.:

Synonyms:4-cyclohexyl-4-[dimethyl(phenyl)silyl]-4-[dimethyl(phenyl)silyloxy]but-1-ene

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Chemical Property of 4-cyclohexyl-4-[dimethyl(phenyl)silyl]-4-[dimethyl(phenyl)silyloxy]but-1-ene

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Technology Process of 4-cyclohexyl-4-[dimethyl(phenyl)silyl]-4-[dimethyl(phenyl)silyloxy]but-1-ene

There total 4 articles about 4-cyclohexyl-4-[dimethyl(phenyl)silyl]-4-[dimethyl(phenyl)silyloxy]but-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 106-95-6
allyl bromide

: 155397-15-2
1,1-biscyclohexanemethanol

: 503606-94-8
4-cyclohexyl-4-[dimethyl(phenyl)silyl]-4-[dimethyl(phenyl)silyloxy]but-1-ene

Guidance literature:: 1,1-biscyclohexanemethanol; With [2,2]bipyridinyl; n-butyllithium; In diethyl ether; hexane; at 0 ℃; for 0.0833333h;

allyl bromide; In diethyl ether; hexane; for 12h;
DOI:10.1002/1522-2675(200210)85:10<3349::AID-HLCA3349>3.0.CO;2-K

Reference yield: 98.0%

: 3839-31-4
dimethyl(phenyl)silyllithium

: 106-95-6
allyl bromide

: 2719-27-9
cyclohexanylcarbonyl chloride

: 503606-94-8
4-cyclohexyl-4-[dimethyl(phenyl)silyl]-4-[dimethyl(phenyl)silyloxy]but-1-ene

Guidance literature:: dimethyl(phenyl)silyllithium; cyclohexanylcarbonyl chloride; In tetrahydrofuran; toluene; at -78 ℃; for 1h;

allyl bromide; In tetrahydrofuran; toluene; at -78 - 20 ℃;
DOI:10.1002/1522-2675(200210)85:10<3349::AID-HLCA3349>3.0.CO;2-K

Reference yield:

: 3839-31-4
dimethyl(phenyl)silyllithium

: 503606-94-8
4-cyclohexyl-4-[dimethyl(phenyl)silyl]-4-[dimethyl(phenyl)silyloxy]but-1-ene

Guidance literature:: Multi-step reaction with 2 steps

1.1: 94 percent / tetrahydrofuran; toluene / -78 °C

2.1: BuLi; 2,2'-bipyridine / hexane; diethyl ether / 0.08 h / 0 °C

2.2: 98 percent / hexane; diethyl ether / 12 h

With [2,2]bipyridinyl; n-butyllithium; In tetrahydrofuran; diethyl ether; hexane; toluene; 2.1: Brook rearrangement;
DOI:10.1002/1522-2675(200210)85:10<3349::AID-HLCA3349>3.0.CO;2-K