trans-carbonyl[(2-naphthyl)(p-tolyl)methoxy]bis(triphenylphosphine)rhodium(I)

Base Information

Chemical Name:trans-carbonyl[(2-naphthyl)(p-tolyl)methoxy]bis(triphenylphosphine)rhodium(I)
CAS No.:405511-53-7
Molecular Formula:C₅₅H₄₅O₂P₂Rh
Molecular Weight:902.814
Hs Code.:

Synonyms:trans-carbonyl[(2-naphthyl)(p-tolyl)methoxy]bis(triphenylphosphine)rhodium(I)

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Chemical Property of trans-carbonyl[(2-naphthyl)(p-tolyl)methoxy]bis(triphenylphosphine)rhodium(I)

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Technology Process of trans-carbonyl[(2-naphthyl)(p-tolyl)methoxy]bis(triphenylphosphine)rhodium(I)

There total 2 articles about trans-carbonyl[(2-naphthyl)(p-tolyl)methoxy]bis(triphenylphosphine)rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 15318-33-9,16353-77-8,13938-94-8
trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I)

: sodium 2-naphthyl-p-tolylmethoxide

: 405511-53-7
trans-carbonyl[(2-naphthyl)(p-tolyl)methoxy]bis(triphenylphosphine)rhodium(I)

Guidance literature:: In tetrahydrofuran; under N2. standard Schlenk techniques; mixt. of Rh complex and ligand (molar ratio 1:3) dissolved in dry THF; stirred at room temp. for 1 h; volatiles removed under reduced pressure; extd. in toluene; filtered through Celite; concd. under reduced pressure; Et2O added slowly; cooled to-35°C; elem. anal.;
DOI:10.1021/ja017401e

Reference yield:

: 15318-33-9,16353-77-8,13938-94-8
trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I)

: 405511-53-7
trans-carbonyl[(2-naphthyl)(p-tolyl)methoxy]bis(triphenylphosphine)rhodium(I)

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran

2: benzene-d6

In tetrahydrofuran; benzene-d6;
DOI:10.1021/ja017401e

Reference yield: 80.0%

: 405511-53-7
trans-carbonyl[(2-naphthyl)(p-tolyl)methoxy]bis(triphenylphosphine)rhodium(I)

: {Rh(μ-CO)(PPh3)2}2

: 136935-71-2
β-naphthyl-4-methylphenyl-ketone

Guidance literature:: In benzene-d6; byproducts: H2; under N2, standard Schlenk techniques; in NMR tube; Rh complex in C6D6 heated at 85°C; not isolated; monitored by (1)H NMR spectra;
DOI:10.1021/ja017401e