dichloro(mesityl)phosphane

Base Information

• Chemical Name: dichloro(mesityl)phosphane
• CAS No.: 6781-96-0
• Molecular Formula: C₉H₁₁Cl₂P
• Molecular Weight: 221.066
• Mol file: 6781-96-0.mol

Synonyms:dichloro(mesityl)phosphane

Chemical Property of dichloro(mesityl)phosphane

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichloro(mesityl)phosphane

There total 14 articles about dichloro(mesityl)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

dimesitylmagnesium (99107-86-5) → dichloro(mesityl)phosphane (6781-96-0)

Guidance literature:

With phosphorus trichloride; Inert atmosphere;

DOI:10.1039/c5dt02825f

Reference yield: 93.0%

2,4,6-trimethylphenyl bromide (576-83-0) → dichloro(mesityl)phosphane (6781-96-0)

Guidance literature:

2,4,6-trimethylphenyl bromide; With magnesium; ethylene dibromide; In tetrahydrofuran; at 20 ℃; for 22h; Reflux; Inert atmosphere;

With zinc(II) chloride; In tetrahydrofuran; at 0 - 20 ℃; for 19h; Inert atmosphere;

With phosphorus trichloride; In tetrahydrofuran; hexane; at 0 ℃; for 1.5h; Inert atmosphere;

DOI:10.1021/jacs.8b13435

Reference yield: 82.0%

Mg(C6H2Me3-2,4,6)2(tetrahydrofuran)2 → dichloro(mesityl)phosphane (6781-96-0) + chloro(bromo)(mesityl)phosphane

Guidance literature:

With phosphorus trichloride; In diethyl ether; at -70 - 20 ℃; Inert atmosphere;

DOI:10.1039/c3dt52373j

upstream raw materials:

1,3,5-trimethyl-benzene

2,4,6-trimethylphenyl bromide

bis(dimethylamino)mesitylphosphine

mesityllithium

Downstream raw materials:

Chloro(diisopropylamino)(2,4,6-trimethylphenyl)phosphane

(Fe(CO)4)2-trans-(P(mesityl))2

trans-{(P(2,4,6-Me₃C₆H₂))2(Cr(CO)5)2}

cis-{(P(2,4,6-Me₃C₆H₂))2(Cr(CO)5)2}