3-benzoyl-benzoic acid 4-(tert-butyl-dimethyl-silanyloxy)-2-methyl-but-2-enyl ester

Base Information

Chemical Name:3-benzoyl-benzoic acid 4-(tert-butyl-dimethyl-silanyloxy)-2-methyl-but-2-enyl ester
CAS No.:618405-30-4
Molecular Formula:C₂₅H₃₂O₄Si
Molecular Weight:424.612
Hs Code.:

3-benzoyl-benzoic acid 4-(<i>tert</i>-butyl-dimethyl-silanyloxy)-2-methyl-but-2-enyl ester

Synonyms:3-benzoyl-benzoic acid 4-(tert-butyl-dimethyl-silanyloxy)-2-methyl-but-2-enyl ester

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Chemical Property of 3-benzoyl-benzoic acid 4-(tert-butyl-dimethyl-silanyloxy)-2-methyl-but-2-enyl ester

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Technology Process of 3-benzoyl-benzoic acid 4-(tert-butyl-dimethyl-silanyloxy)-2-methyl-but-2-enyl ester

There total 4 articles about 3-benzoyl-benzoic acid 4-(tert-butyl-dimethyl-silanyloxy)-2-methyl-but-2-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 579-18-0
3-benzoylbenzoic acid

: 162188-27-4
(2E)-4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-methyl-2-buten-1-ol

: 618405-30-4
3-benzoyl-benzoic acid 4-(tert-butyl-dimethyl-silanyloxy)-2-methyl-but-2-enyl ester

Guidance literature:: With dmap; diisopropyl-carbodiimide; In dichloromethane; at 20 ℃;
DOI:10.1021/ja036178d

Reference yield:

: 114701-65-4
tert-butyldimethyl((3-methylbut-2-en-1-yl)oxy)silane

: 618405-30-4
3-benzoyl-benzoic acid 4-(tert-butyl-dimethyl-silanyloxy)-2-methyl-but-2-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: SeO₂; t-BuOOH; salycylic acid / CH₂Cl₂; H₂O; various solvent(s) / 12 h

1.2: 69 percent / NaBH₄ / methanol

2.1: 93 percent / DMAP; diisopropylcarbodiimide / CH₂Cl₂ / 20 °C

With tert.-butylhydroperoxide; dmap; selenium(IV) oxide; salicylic acid; diisopropyl-carbodiimide; In dichloromethane; water; 2.1: Steglich reaction;
DOI:10.1021/ja036178d

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 618405-30-4
3-benzoyl-benzoic acid 4-(tert-butyl-dimethyl-silanyloxy)-2-methyl-but-2-enyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: 100 percent / i-Pr₂NEt / CH₂Cl₂ / 20 °C

2.1: SeO₂; t-BuOOH; salycylic acid / CH₂Cl₂; H₂O; various solvent(s) / 12 h

2.2: 69 percent / NaBH₄ / methanol

3.1: 93 percent / DMAP; diisopropylcarbodiimide / CH₂Cl₂ / 20 °C

With tert.-butylhydroperoxide; dmap; selenium(IV) oxide; N-ethyl-N,N-diisopropylamine; salicylic acid; diisopropyl-carbodiimide; In dichloromethane; water; 3.1: Steglich reaction;
DOI:10.1021/ja036178d