toluene-4-sulfonic acid (1S,5S)-6-[1,3]dithian-2-yl-5-hydroxy-1-[2-(4-methoxybenzyloxy)ethyl]-3-methylene-hexyl ester

Base Information

Chemical Name:toluene-4-sulfonic acid (1S,5S)-6-[1,3]dithian-2-yl-5-hydroxy-1-[2-(4-methoxybenzyloxy)ethyl]-3-methylene-hexyl ester
CAS No.:617715-05-6
Molecular Formula:C₂₈H₃₈O₆S₃
Molecular Weight:566.804
Hs Code.:

Synonyms:toluene-4-sulfonic acid (1S,5S)-6-[1,3]dithian-2-yl-5-hydroxy-1-[2-(4-methoxybenzyloxy)ethyl]-3-methylene-hexyl ester

Suppliers and Price of toluene-4-sulfonic acid (1S,5S)-6-[1,3]dithian-2-yl-5-hydroxy-1-[2-(4-methoxybenzyloxy)ethyl]-3-methylene-hexyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of toluene-4-sulfonic acid (1S,5S)-6-[1,3]dithian-2-yl-5-hydroxy-1-[2-(4-methoxybenzyloxy)ethyl]-3-methylene-hexyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of toluene-4-sulfonic acid (1S,5S)-6-[1,3]dithian-2-yl-5-hydroxy-1-[2-(4-methoxybenzyloxy)ethyl]-3-methylene-hexyl ester

There total 1 articles about toluene-4-sulfonic acid (1S,5S)-6-[1,3]dithian-2-yl-5-hydroxy-1-[2-(4-methoxybenzyloxy)ethyl]-3-methylene-hexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: toluene-4-sulfonic acid (5S)-5-(tert-butyldimethylsilanyloxy)-6-[1,3]dithian-2-yl-1-[2-(4-methoxybenzyloxy)-ethyl]-3-methylenehexyl ester

: 617715-05-6
toluene-4-sulfonic acid (1S,5S)-6-[1,3]dithian-2-yl-5-hydroxy-1-[2-(4-methoxybenzyloxy)ethyl]-3-methylene-hexyl ester

Guidance literature:: With pyridine hydrofluoride; In acetonitrile; at 20 ℃; for 16h; Inert atmosphere;
DOI:10.1016/j.tet.2011.05.020

Reference yield: 73.0%

: 617715-05-6
toluene-4-sulfonic acid (1S,5S)-6-[1,3]dithian-2-yl-5-hydroxy-1-[2-(4-methoxybenzyloxy)ethyl]-3-methylene-hexyl ester

: 617715-06-7
(2S,6R)-2-[1,3]dithian-2-ylmethyl-6-[2-(4-methoxybenzyloxy)ethyl]-4-methylenetetrahydropyran

Guidance literature:: With sodium hydride; In mineral oil; benzene; at 90 ℃; for 40h; Inert atmosphere;
DOI:10.1016/j.tet.2011.05.020

Reference yield:

: 617715-05-6
toluene-4-sulfonic acid (1S,5S)-6-[1,3]dithian-2-yl-5-hydroxy-1-[2-(4-methoxybenzyloxy)ethyl]-3-methylene-hexyl ester

: 617714-96-2
(2R,5S,8S)-8,10-bis(tert-butyldimethylsilyloxy)-1-((2S,6R)-6-(2-(4-methoxybenzyloxy)ethyl)-4-methylenetetrahydro-2H-pyran-2-yl)-5-methyl-4-methylenedecan-2-ol

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium hydride / mineral oil; benzene / 40 h / 90 °C / Inert atmosphere

2.1: water; calcium carbonate; methyl iodide / acetonitrile / 20 °C

3.1: dichloromethane / 1.58 h / -78 °C / Inert atmosphere

3.2: -78 - 20 °C / Inert atmosphere

With water; sodium hydride; calcium carbonate; methyl iodide; In dichloromethane; acetonitrile; mineral oil; benzene;
DOI:10.1016/j.tet.2011.05.020