[closo-1-Ph-3,8-(PPh₃)2-3-Cl-3-H-3,1,2-RhC₂B₉H₉]*0.5(benzene)

Base Information

Chemical Name:[closo-1-Ph-3,8-(PPh₃)2-3-Cl-3-H-3,1,2-RhC₂B₉H₉]*0.5(benzene)
CAS No.:89462-05-5
Molecular Formula:C₄₄H₄₅B₉ClP₂Rh
Molecular Weight:910.503
Hs Code.:

[closo-1-Ph-3,8-(PPh<sub>3</sub>)2-3-Cl-3-H-3,1,2-RhC<sub>2</sub>B<sub>9</sub>H<sub>9</sub>]*0.5(benzene)

Synonyms:[closo-1-Ph-3,8-(PPh₃)2-3-Cl-3-H-3,1,2-RhC₂B₉H₉]*0.5(benzene)

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Chemical Property of [closo-1-Ph-3,8-(PPh₃)2-3-Cl-3-H-3,1,2-RhC₂B₉H₉]*0.5(benzene)

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Technology Process of [closo-1-Ph-3,8-(PPh₃)2-3-Cl-3-H-3,1,2-RhC₂B₉H₉]*0.5(benzene)

There total 3 articles about [closo-1-Ph-3,8-(PPh₃)2-3-Cl-3-H-3,1,2-RhC₂B₉H₉]*0.5(benzene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 14694-95-2
tris(triphenylphosphine)rhodium(l) chloride

: 39336-45-3
(CH₃)4N⁽¹⁺⁾*(C₆H₅)C₂B₉H₁₁^(1-)=(CH₃)4N(C₆H₅C₂B₉H₁₁)

: 89462-05-5
[closo-1-Ph-3,8-(PPh₃)2-3-Cl-3-H-3,1,2-RhC₂B₉H₉]*0.5(benzene)

Guidance literature:: With triphenylphosphine; HBF₄; benzene; In ethanol; water; to mixt. of educts and PPh3 added EtOH followed by 48% aq. HBF4, heatedto reflux temp. for 7 h, allowed to cool to ca. 40°C; ppt. isolated by filtration, washed with EtOH and Et2O, recrystd. from benzene/EtOH; elem. anal.;
DOI:10.1021/ja00322a038

Reference yield:

: 65337-89-5,62860-11-1,62817-24-7
3,3-{(C₆H₅)3P}2-3-H-3,1,2-RhC₂B₉H₁₀-1-C₆H₅

: 89462-05-5
[closo-1-Ph-3,8-(PPh₃)2-3-Cl-3-H-3,1,2-RhC₂B₉H₉]

Guidance literature:: With CH₂Cl₂; In n-heptane; dichloromethane; recrystd. by layering heptane over CH2Cl2 soln. of Rh complex; crystals sepd. mechanically;
DOI:10.1021/ja00322a038