[(HO)(NH₂(CH₂)2NH₂)2Co(PO₄)Co(NH₂(CH₂)2NH₂)2(O₃POC₆H₄NO₂)]

Base Information

• Chemical Name: [(HO)(NH₂(CH₂)2NH₂)2Co(PO₄)Co(NH₂(CH₂)2NH₂)2(O₃POC₆H₄NO₂)]
• CAS No.: 93000-36-3
• Molecular Formula: C₁₄H₃₇Co₂N₉O₁₁P₂
• Molecular Weight: 687.435
• Mol file: 93000-36-3.mol

Synonyms:[(HO)(NH₂(CH₂)2NH₂)2Co(PO₄)Co(NH₂(CH₂)2NH₂)2(O₃POC₆H₄NO₂)]

Chemical Property of [(HO)(NH₂(CH₂)2NH₂)2Co(PO₄)Co(NH₂(CH₂)2NH₂)2(O₃POC₆H₄NO₂)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(HO)(NH₂(CH₂)2NH₂)2Co(PO₄)Co(NH₂(CH₂)2NH₂)2(O₃POC₆H₄NO₂)]

There total 5 articles about [(HO)(NH₂(CH₂)2NH₂)2Co(PO₄)Co(NH₂(CH₂)2NH₂)2(O₃POC₆H₄NO₂)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

rac-bis(μ-4-nitrophenyl phosphato)bis[bis(1,2-ethanediamine)cobalt(III)] → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + {Co(ethylenediamine)2(OH)2}(1+) + trans-hydroxo(4-nitrophenyl phosphato)bis(1,2-ethanediamine)cobalt(III) (87183-66-2,93060-62-9) + cis-hydroxo(4-nitrophenyl phosphato)bis(1,2-ethanediamine)cobalt(III) + [(HO)(NH2(CH2)2NH2)2Co(PO4)Co(NH2(CH2)2NH2)2(O3POC6H4NO2)] (93000-36-3)

Guidance literature:

With NaOH; In water; water-d2; temp. of soln. of educt in H2O/D2O adjusted to 25°C, soln. of NaOH added rapidly to 0.5 M concn. of OH(1-) / further products; not isolated; monitored by NMR;

DOI:10.1021/ja00337a026

Reference yield:

rac-bis(μ-4-nitrophenyl phosphato)bis[bis(1,2-ethanediamine)cobalt(III)] chloride → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + [Co(ethylenediamine)2(H2O)2](3+) (18485-07-9,18485-08-0,19314-32-0,45837-92-1,21247-59-6,21242-06-8) + trans-aqua(4-nitrophenyl phosphato)bis(1,2-ethanediamine)cobalt(III) ion (87183-70-8,93060-70-9) + cis-aqua(4-nitrophenyl phosphato)bis(1,2-ethanediamine)cobalt(III)ion + [(HO)(NH2(CH2)2NH2)2Co(PO4)Co(NH2(CH2)2NH2)2(O3POC6H4NO2)] (93000-36-3)

Guidance literature:

With NaOH; water; In water; byproducts: 4-nitrophenyl phosphate; educt dissolved in water at 25°C, 3 M NaOH soln. rapidly added with stirring, quenched after 4t1/2 by addn. of 2 M HClO4 to pH ca. 3.8; dild. with ice-cold water, chromd. (Sephadex C-25/Na(1+), ice-cold water(pH 3.8 with 0.005 M acetate buffer), 0.1-0.4 M NaClO4 (pH 4)); Kinetics;

DOI:10.1021/ja00337a026

Reference yield:

meso-bis(μ-4-nitrophenyl phosphato)bis[bis(1,2-ethanediamine)cobalt(III)] (93060-59-4,93060-60-7,93060-68-5) → mono-p-nitrophenyl phosphate (330-13-2) + trans-hydroxo(4-nitrophenyl phosphato)bis(1,2-ethanediamine)cobalt(III) (87183-66-2,93060-62-9) + cis-hydroxo(4-nitrophenyl phosphato)bis(1,2-ethanediamine)cobalt(III) + [(HO)(NH2(CH2)2NH2)2Co(PO4)Co(NH2(CH2)2NH2)2(O3POC6H4NO2)] (93000-36-3)

Guidance literature:

With NaOH; In water; water-d2; temp. of soln. of educt in H2O/D2O adjusted to 5.+-.1°C, soln. of NaOH added rapidly to 0.2 M concn. of OH(1-), reacted for 1210 s; not isolated; monitored by NMR; Kinetics;

DOI:10.1021/ja00337a026

upstream raw materials:

meso-bis(μ-4-nitrophenyl phosphato)bis[bis(1,2-ethanediamine)cobalt(III)]

Downstream raw materials:

4-nitro-phenol

mono-p-nitrophenyl phosphate