tert-Butyl (3-ethylfuran-2-yl)carbamate

Base Information

Chemical Name:tert-Butyl (3-ethylfuran-2-yl)carbamate
CAS No.:704913-86-0
Molecular Formula:C₁₁H₁₇NO₃
Molecular Weight:211.261
Hs Code.:
DSSTox Substance ID:DTXSID401184758
Mol file:704913-86-0.mol

Synonyms:tert-Butyl (3-ethylfuran-2-yl)carbamate;704913-86-0;DTXSID401184758;Carbamic acid, (3-ethyl-2-furanyl)-, 1,1-dimethylethyl ester

Suppliers and Price of tert-Butyl (3-ethylfuran-2-yl)carbamate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of tert-Butyl (3-ethylfuran-2-yl)carbamate

Chemical Property:

PSA：51.47000
LogP:3.26200
XLogP3:2.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:211.12084340
Heavy Atom Count:15
Complexity:222

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCC1=C(OC=C1)NC(=O)OC(C)(C)C

Technology Process of tert-Butyl (3-ethylfuran-2-yl)carbamate

There total 5 articles about tert-Butyl (3-ethylfuran-2-yl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 31199-03-8
1,1-dimethoxypentan-3-one

: 704913-86-0
tert-butyl (3-ethyl-furan-2-yl)carbamate

Guidance literature:: Multi-step reaction with 5 steps

1.1: NaOMe / diethyl ether / 20 °C

1.2: 49 percent / 170 °C

2.1: 94 percent / aq. NaOH / 2 h / Heating

3.1: oxalyl chloride; DMF / CH₂Cl₂ / 1 h / 20 °C

4.1: NaN₃ / diethyl ether; H₂O / 3 h

5.1: 1.6 g / 12 h / Heating

With sodium hydroxide; sodium azide; oxalyl dichloride; sodium methylate; N,N-dimethyl-formamide; In diethyl ether; dichloromethane; water;
DOI:10.1021/jo060238r

Reference yield:

: 704913-84-8
3-ethyl-furan-2-carboxylic acid methyl ester

: 704913-86-0
tert-butyl (3-ethyl-furan-2-yl)carbamate

Guidance literature:: Multi-step reaction with 4 steps

1: 94 percent / aq. NaOH / 2 h / Heating

2: oxalyl chloride; DMF / CH₂Cl₂ / 1 h / 20 °C

3: NaN₃ / diethyl ether; H₂O / 3 h

4: 1.6 g / 12 h / Heating

With sodium hydroxide; sodium azide; oxalyl dichloride; N,N-dimethyl-formamide; In diethyl ether; dichloromethane; water;
DOI:10.1021/jo060238r

Reference yield:

: 704913-85-9
3-ethyl-furan-2-carboxylic acid

: 704913-86-0
tert-butyl (3-ethyl-furan-2-yl)carbamate

Guidance literature:: Multi-step reaction with 3 steps

1: oxalyl chloride; DMF / CH₂Cl₂ / 1 h / 20 °C

2: NaN₃ / diethyl ether; H₂O / 3 h

3: 1.6 g / 12 h / Heating

With sodium azide; oxalyl dichloride; N,N-dimethyl-formamide; In diethyl ether; dichloromethane; water;
DOI:10.1021/jo060238r