phenoxy-4-prop-1-ynylbenzene

Base Information

• Chemical Name: phenoxy-4-prop-1-ynylbenzene
• CAS No.: 60319-82-6
• Molecular Formula: C₁₅H₁₂O
• Molecular Weight: 208.26
• Mol file: 60319-82-6.mol

Synonyms:phenoxy-4-prop-1-ynylbenzene

Chemical Property of phenoxy-4-prop-1-ynylbenzene

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of phenoxy-4-prop-1-ynylbenzene

There total 1 articles about phenoxy-4-prop-1-ynylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

1-(4-ethynylphenoxy)benzene (4200-06-0) + methyl iodide (74-88-4) → phenoxy-4-prop-1-ynylbenzene (60319-82-6)

Guidance literature:

1-(4-ethynylphenoxy)benzene; With n-butyllithium; In tetrahydrofuran; at -78 - 20 ℃;

methyl iodide; at -78 ℃; for 1h;

DOI:10.1039/c2ob26295a

Reference yield: 95.0%

phenoxy-4-prop-1-ynylbenzene (60319-82-6) → 1,2,4-trimethyl-3,5,6-tri-(4-phenoxyphenyl)benzene

Guidance literature:

With bis(acetylacetonate)nickel(II); 1,3-dibenzylimidazolium bromide; butyl magnesium bromide; In tetrahydrofuran; toluene; at 60 ℃; for 1h; regioselective reaction; Inert atmosphere; Schlenk technique;

DOI:10.1002/asia.201601469

Reference yield: 85.0%

2-(ferrocene-2-yl)quinoline + phenoxy-4-prop-1-ynylbenzene (60319-82-6) → C34H27FeNO

Guidance literature:

With C₆₀H₅₉N₂ScSi; trityl tetrakis(pentafluorophenyl)borate; In toluene; at 80 ℃; for 48h; enantioselective reaction; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1021/jacs.0c13166

upstream raw materials:

1-(4-ethynylphenoxy)benzene

methyl iodide

Downstream raw materials:

1-phenoxy-4-(prop-1-en-1-yl)benzene

methyl 2,4-dimethyl-5-(4-phenoxyphenyl)furan-3-carboxylate