(2-Benzoyl-3-methyl-3-trimethylsilanyl-cycloprop-1-enyl)-phenyl-methanone

Base Information

Chemical Name:(2-Benzoyl-3-methyl-3-trimethylsilanyl-cycloprop-1-enyl)-phenyl-methanone
CAS No.:198643-11-7
Molecular Formula:C₂₁H₂₂O₂Si
Molecular Weight:334.49
Hs Code.:

Synonyms:(2-Benzoyl-3-methyl-3-trimethylsilanyl-cycloprop-1-enyl)-phenyl-methanone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2-Benzoyl-3-methyl-3-trimethylsilanyl-cycloprop-1-enyl)-phenyl-methanone

Chemical Property:

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Technology Process of (2-Benzoyl-3-methyl-3-trimethylsilanyl-cycloprop-1-enyl)-phenyl-methanone

There total 7 articles about (2-Benzoyl-3-methyl-3-trimethylsilanyl-cycloprop-1-enyl)-phenyl-methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 198643-14-0
[2-(Hydroxy-phenyl-methyl)-3-methyl-3-trimethylsilanyl-cycloprop-1-enyl]-phenyl-methanol

: 198643-11-7
(2-Benzoyl-3-methyl-3-trimethylsilanyl-cycloprop-1-enyl)-phenyl-methanone

Guidance literature:: With manganese(IV) oxide; In dichloromethane;
DOI:10.1016/S0040-4039(97)01801-7

Reference yield:

: 52685-47-9
(Z)-3-(trimethylsilyl)but-2-en-1-ol

: 198643-11-7
(2-Benzoyl-3-methyl-3-trimethylsilanyl-cycloprop-1-enyl)-phenyl-methanone

Guidance literature:: Multi-step reaction with 5 steps

1: 76 percent / oxalyl chloride, N,N-dimethylformamide / hexane

2: 20 percent / sodium amide / tetrahydrofuran / 45 °C

3: 78 percent / methyllithium / -78 °C

4: 61 percent / methyllithium

5: 78 percent / MnO₂ / CH₂Cl₂

With manganese(IV) oxide; oxalyl dichloride; methyllithium; sodium amide; N,N-dimethyl-formamide; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1016/S0040-4039(97)01801-7

Reference yield:

: 13411-48-8
1-(trimethylsilyl)ethanone

: 198643-11-7
(2-Benzoyl-3-methyl-3-trimethylsilanyl-cycloprop-1-enyl)-phenyl-methanone

Guidance literature:: Multi-step reaction with 7 steps

1: 71 percent / LDA, HMPA / tetrahydrofuran

2: 83 percent / LiAlH₄ / diethyl ether

3: 76 percent / oxalyl chloride, N,N-dimethylformamide / hexane

4: 20 percent / sodium amide / tetrahydrofuran / 45 °C

5: 78 percent / methyllithium / -78 °C

6: 61 percent / methyllithium

7: 78 percent / MnO₂ / CH₂Cl₂

With N,N,N,N,N,N-hexamethylphosphoric triamide; manganese(IV) oxide; lithium aluminium tetrahydride; oxalyl dichloride; methyllithium; sodium amide; N,N-dimethyl-formamide; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; hexane; dichloromethane;
DOI:10.1016/S0040-4039(97)01801-7